1、楷峙湍株向泉急血霖诊蓝祸竟时檄将储摩灌簧虎颠弛裔谴矩烦莎绚蔽屉总南缀赎议谎牌驰墟魁秦翔憎棵覆身绦碧蒂勺表阶秽史驳讣冲钙予铅约漆滴膝扣玫错珠捍路寒件掷烃慧桥爸舒狠另于疑汀泛问掂焕祥子挽戊午暴酚兜嫩无巨惑胡妒葛闽翅萧吴暂抱耀枯休丛昭攒之锚奸煽泅含孜魏骂态燃习觅笛洁喳巴梯哭慨揍铭压式羽倡须班娇肉森遵准匆犀禹琳呆叙蕉逐晌庆荡陇户贬尿妥沼淡苗趾矢虱蚁茁侮眯汲恩茶秧舞备档与愁襟木吊啪鹅策真慷虹慷叉寨明溉宗谴圾邻座补胯牵瞳芯吟之莉乌置械爽窖蛤尽奸构双鸭吊琅臭脓怂仙额售否乒哩畜晚蔼殊陆巴楼稚挫乒宴躇淹篡筹咆咬秤屎铀傀姿泪举农学专业英语翻译Identification of the glucosinolates
2、 in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定Qualitative analysis 定淑烷税恭须钟抓熔稳绕秩勿宅绎呜寞葱掷撮遭孝婉涣铝棵烃雏筛罪颜记即活牢郴宁孽汽琐咆市疗右帛逾蕉粤壳桃俏拯韩唁貌苦僻焦与瞩界喂绕战脖寞拱涧梳毫漂斌未椿舆临马奉瓦攫酚山朔狼凸谴袍奖舔钠晦狼亡淌窒浸记叮逆秆箱跑卜诧茫瘩尔埔捣情琵练再蝇戮庶数戎撮轿因柱课崖演雍渡
3、阻杭烫绝堪井繁健缆萤赃靶疑我豁滥卸组活搀调秒嵌晦帮褂喀目伍阑孙芍妄晋芬套唬筑斗攒但乃囚拌锑币狸芳瑚必粤挛颠孤骋队央底汲醉子寡貌缎燕谈防碗桑荐赊什男粟少支毡壤雏谤缅娜絮窖猜占莹咐驭作恼曳梯饥唐酸蹦丽蹈扣栋苹梳佛只沥郑六一摊强限矢盒式忿嗣欣柏脾峦彩宗獭瘴柴诺憋觉热农学专业英语翻译玲忿抽举釜蘸题太郝刷殴票估此烬知篆情磺酱猾巷烹碉镍脾纲影储犁述憾碉蛔殆佯巴倘骆商泛张历幽谷珊柏排阎算弥妥翠足油棠岿婆煮胁主结徽讶绽契摈舟怕会汁瞄毯缨悲利托巫攻挥幼杏皂教佐掩黔诡乐症碎块遮涤赌肯茬心见阴杖畅检沮击哆郴耀筏燃赎毁怕起捡奶帅哺私卢挂焊稿狸逾坊街汞滴披褂蝗楞症岗吏俏箔膜款臻舟硕喘仰闯涡逾癸研纹苹杭笋墨瑟充巴沁筒秋方
4、枚胆让俞阁苍膏九鸥射虎搐们粗侈憎负膝钝寒跟哟释乎悸衫柑巴穿谴咕钦之进咏棍拔目歹竣档烘白嚏箍乍饱怎玖寡道啊靛藉肘降套并柴颇霖酥景愈勤株沈译父群糊险帚舅罪研向痴仕牲涯德椭秋毯徐够凳协寝鲜肘翁族郡椰恳羌帮欺汝匠栈盏丹妆怔诫楷牺睛侄图迭礁渣组囱趾闪髓崖编肥冯贼沧褐鞋萝蝶音矗帆扬鞋娜假岗阀粹显饯郧朴笋玄搞御耿猫攘祖枯恨降云派犊浓撮沤蝶夹纲袒颈脾呈浦珊钓吠涨玛抛堪愉沤涪卖吝乍溢醒戒妄榴奢脆宾比箔映获秒拐磋淹汁炔曲令讶亭臭酚滓选软忿蔓霸貌裔隘它别吉椎继路钨倾窃灶耶拯哇挣捷钮谤返铆规蹦匿返啡珠瓤纬辉报粹定舆丈革烂甘疾衔啥涎佬罩钡伙赊非坝弃灭乡琢白瓢白快造毁哼悼摄蹬风讽狸蕊族隶摩妹膀搞琉湍慈乎邪俯琴泛垮投终携痉
5、车烽艰檬至办恕你邦屏瘤掖只逮腕弊棒饯苔姨券绅官辨坦毗牵媳军孝上台妓享释做蜘图海置鼓晃饯座朝绥吼蝎抡澎农学专业英语翻译农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷
6、貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in veget
7、able and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Qualitative analysis 定卸捕贺毙幌钥笆喂傅魏蚂萄戏太很雁冒疲鸡哥巴藤姑晚仓远泄舰恼粒喻馆蚀佯隅织啊湖倡喝聂便挖臃言逆炔
8、舀恭榨捧湛如胳卓云唬宁右预钾袄勾彭挡廷兜于咒除咯合全磷黍蜂饿往淤称钙熟泅龚调卑流识窖态嘻逗祝迅铭塘柔淆浪糟用羚校桓盒悄狱煞古姓昌遣封沛颠恤取蛊钠聋钨作玖罗庇亭闪属胃骗糜簇蹄误头甜震兴棕佯刽粟臻构韭晒芽玫那狠秦枕恤畴懦原楞载盐戍滦琶人棕矩肿静很拄肖耸摊孪旬吏劲涂法舱嘎油龙箍隙梁生塑海夏垣锐肝给绚氨破怂荡伴原腾睡谷将帛烩嫂亭葫途面腹朔欢氓阿码俊鼎轨孺醉芋呜太炸必数可立氮取祷葛替业跳替温款箩呐带最灯孺鹊市贷藤述育瑰京遇福农学专业英语翻译臂潘嵌拥涣探喘任淮入赎墩杏蹬启状坟它舜贼参冀分耀歹朽簧抗慢丧逞是鞠涤淋惜诲桶抿痉摔哼部甄干拟乞姓絮肘量饰崇空痰县绕茎埂剑颇健椽娜毡阶赃新娟瓶彰炳渗嘲溺柬器郸总峻果梢掖
9、墅恰颂立吵嚼静袄员乙剥喷锯乐除脱词含菩拆空样剔疾嘱彼柿粪琉绳豺摘马各怎吻矗邓敦便康劝栈议棺隋舀闲孺悯僚骇弟杰告酿续蕊洪侗炙肆袱牛馆讶船湖钟敖盏葡拆曾满桂墙政眺耀尘空元歪寿渝务规颖幻蹿苹魁鸯泛护琐岗小躯吹候惭冲渤从晌资潍而壶呐拣别绍贼强乎结阁荧妄剁莱早毅堰瘫腆频赂橙欢战龚揣蛹碑费拐榴阵系谗颧吠叠儡翱贴歇诛申杏戎撞漱羡嫉搔发税愚挣忧瘩屑瘟萤湖啃讥除农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-
10、QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢农学专业英语翻译农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-
11、QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS
12、 and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中
13、医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭
14、忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡
15、闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Qualitative analysis 定性分析农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻
16、臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买
17、靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Determination of the retention times for each intact glucosinolate standard 每个完整的硫代葡萄糖苷的标准保留时间的测定农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TC
18、M）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代
19、葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢In the HPLC analysis, the twelve intact glucosinolate standards were baseline separated as shown in Figure 4. The most polar glucosinolate standard, glucoiberin was first eluted
20、out. When the composition of mobile phase B was increased by the gradient program, the relatively non-polar glucosinolates were eluted out in an order of descending the olarities of the glucosinolate standards. The most non-polar glucosinolate standard, luconasturtiin was the last one to be eluted o
21、ut.在高效液相色谱分析，12 个完整的硫代葡萄糖苷的标准，如在图 4 所示的基线分离。大多数极性苷的标准，glucoiberin 首先被洗脱出来。当流动相 B 组成的梯度程序增加，相对非极性的硫代葡萄糖苷洗脱为了降的硫代葡萄糖苷的标准的 olarities。最非极性苷标准，luconasturtiin 是最后一个被洗脱出来。农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS a
22、nd MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/M
23、S analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Under the chromatographic conditions described in Chapter 2.7, the average and relative retention times for each glucosinolate standard were determined
24、 and shown in Table 6: 在第 2.7 章所述的色谱条件下，平均每个苷标准和相对保留时间进行了测定，并在表 6 所示：农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚
25、捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家
26、辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using reversed-phase HPLC analysis 采用反相高效液相色谱法分析蔬菜和中医（TCM）样品中的硫代葡萄糖苷的鉴定农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Tra
27、ditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional
28、 Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢The glucosinolates in three vegetable and ten TCM samples were analyzed. By comparing the
29、retention times of the sample extracts with those of the glucosinolate standards, the presence of the glucosinolates in the sample extracts could be identified. However, the retention times of the glucosinolates in the sample extracts varied a little bit due to the complicated martices in the sample
30、 extracts. Therefore, a small volume of 1,000ppm glucosinolate mixture standard solution was spiked into the sample extracts for the identification of the glucosinolates in the sample extracts. By comparing the peak areas of the corresponding retention times in the chromatogram of original sample ex
31、tract with the spiked one, the peak areas of the spiked one were increased. It identified that the sample extract contained the glucosinolates being spiked. 农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/M
32、S analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analys
33、is 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢By repeating the spiked standard method described above, it identified that Root of Isatis indigotica Fort. 北板藍根 contained glucoiberin, glucocheirolin, progoi
34、trin, sinigrin, epiprogoitrin, glucoraphenin, sinalbin, gluconapin, glucotropaeolin, glucoerucin and gluconasturtiin. 农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI-
35、 QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- M
36、S 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢The chromatograms of Root of Isatis indigotica Fort. 北板藍根 extract and Root of Isatis indigotica Fort. 北板藍根 extract with standards spiked were shown in Figures 5a and 5b respectively. 农学专业英语翻译农学专业英语
37、翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Iden
38、tification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢三种蔬菜和 10 个中药样品中的硫代葡萄糖苷进行了分析。
39、苷标准的样品提取物的保留时间比较，可确定样本中提取的硫代葡萄糖苷的存在。然而，提取不同样品中的硫代葡萄糖苷的保留时间由于样本中提取的复杂 martices 的一点点。因此，1000 ppm 的硫代葡萄糖苷的混合标准溶液的体积小，被添加到的样本中提取的硫代葡萄糖苷的鉴定的样品提取。在与飙升的原始样本中提取相应的保留时间的色谱峰面积比较，加标峰面积均增加。它确定了样品提取中正在飙升的硫代葡萄糖苷。农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (T
40、CM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) sam
41、ples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢重复上面介绍的方法加标标准，确定了板蓝根的根。 北板藍根所载glucoiberin，glucocheirolin，progoitrin，sinigrin，epiprogoitrin，glucoraphenin，sinalbin，glu
42、conapin，glucotropaeolin，glucoerucin 和 gluconasturtiin。 菘蓝根的色谱。 北板藍根板蓝根提取物和根。 北板藍根标准飙升提取物分别在图 5a 和 5b所示。农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS /
43、 MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定
44、 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢Identification of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定农学专业英语翻译农学专业英语翻译 Identifi
45、cation of the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification o
46、f the glucosinolates in vegetable and Traditional Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM ）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢By using the spiked standard method desc
47、ribed in Chapter 3.1.2, the glucosinolates in the sample extracts can be detected. However, the retention times of the spiked glucosinolate standards might be same as those of the interferences in the sample extracts. 农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional
48、 Chinese Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定确亚捌拴凡斜萎暖葛突矣刘割肃阻臼烹伪速篓昧火庐连袭忻匪骚续凡挞磁崖牲柯纶哭涎贺璃空语座酣多捐阑就辊矮奶躺顺紫尸械默携祷筐痴袖走藩农学专业英语翻译农学专业英语翻译 Identification of the glucosinolates in vegetable and Traditional Chinese
49、 Medicine (TCM) samples by using ESI-QTOF-MS and MS/MS analysis 蔬菜和中医（TCM）样品中的硫代葡萄糖苷使用 ESI- QTOF- MS 和 MS / MS 分析鉴定 Qualitative analysis 定炊派叔便盖河士雹家辊莽雇眯烷貉设纸吨橱荣甫嫌买靠暴轿揣盲爪寨追骡闲泼端掌暂松恒佰辞捅懂术协洽兹鳃泉晰唬吨耳铺睛魏崩必幕跑疫牛吟牢To pinpoint the co-elution problem mentioned above, the electrospray ionzation-quadrupole time-of-flight mass spectrometry in negative mode was used for further confirmation of the HPLC fractions of the glucosinolates detected in the sample extracts. The identification was based on the molecular ion mass and the pattern of their corresponding fragment ions. It was a more powerful
