1、 EBc $ B “ “Ba 1“1a : QZ_KvK#Hq Y M V ?2a Q qQ V ?MC LbH2 1/2O2= H2O(l) = -237.2 KJ/mol = 3.791041mrGaKmrGaKNaOH HCl = NaCl H2O = -79.9 KJ/mol = 1.011014=a “ay Q qY iaab4a 4a;vaQ UQ ?1“a “ ? eQ PQ qi ba ?Ze NB 4 E W=1 T p D T 4 ? Qb k m ?9QV 4_4V = E W -=1 Q QasaQ Q 1i 9QQFb Q?C P V9Q Q LC V4_4Vb= 4
2、 = E W E M1 V 0as0 ;/ ?Zs0Q S E ! s0 ZE T D S SE H Mv:bQ qV UEiDtHWQdPdtdRdttQ i HWMQ ql!Q RP RP0 (0) (0)tn n=Rp( ) ( ) ttnt nt=pPRR() (0)() (0)nt nnt n= =dt)t(dn1dt)t(dn1dtdPR=1111 1 1 1 1 22BddAdBrVdt a dt b dteE fF gG hHdE dF dG dH dBredt f dt gdt hdt r dtdd drdt dt dtdp dp dprdt dt dtr= =+=+= =
3、= = = /0 /0 0Q ql iQ MQ/ 0 H / 0 H 0 H/0 /0 0,r i HW HW X 8SS 35=aQ q wL HWQ iM wLV7Q HW qbQ 7 St=0 H qQ B1 bZE a aFE4“ b4 ZE iL1“ Vs 6Q qZBaQdQQdQQQs0 MT 3s0dQ QQ22 2222H +Cl =2HCl Cl 2Cl MCl+ H = HCl HH Cl HCl Cl2Cl M Cl MM+= + =+= +=a T p Q Q qQ i 1b QZQ“ bQ qZQ q iW1“ TdQ qZ LQ ZE21122223322244(
4、1) Cl M 2Cl M r = Cl M(2) Cl H =HCl H r = ClH (3) H Cl HCl Cl r = HCl (4) 2Cl M=Cl M r = Cl Mkkkk+= += +aQ) aQs0 Q q 1aQ) qZQ i 0rk= ,)QA rk= B)QAB , A Brk= =) B)2A B , A , Brk= ) =) B)-2AB rk= B)Q1/2AB 1.5rk= )Q2aQs0 Q L=FQs0 “Qs0 bQs0 V uss0Qas0Q s0QQs0 V ? e baQ q qZ1 “ L Q q il Q i ( i H LQ qyN
5、Q i1 L QaQ4ab41 . Q a7sL “Q) 7b e) QBaB)Qfirst order reactionQ q Q iBQZ11A P0 0d( )dlt a t t a x x xka xt =B)Q qZs Ts T11100n( )dd ln()xtax ktxakt ktax ax=+= = s T11111ln( )2ln3ln24=kax t kaax ktax =a TmL| qa Q iQ HW1“a q HWa B)U QQ + S i1:1112111ln ln 0.0050714 1 6.85%ln 2 ln 2136.70.0050711 1 1ln
6、ln 454.21 0.00507 1 90%aaxtdktyddk= = =5 b E b k pN zM 1s V HW L U=a =)QQ qZ i Q=)Q222A P 2A )2(AB PBA )1(krkr=+22222220022(1) A B P 0 0 d()()ddd ()dd()d1d()11xtt a b t t a - x b - x x xka xb xtabxka xtktaxkt xktaaxxktax -x a+= =+= J H 2111122213 724 8()1111231: 137abtaxkt a-x attkattt=:=)Q +a TmL|
7、qLaQ i HW1“ Ta q i HW a Q S iQ1 %+2200222(1) A B P 0 0 d1ln1l()(n)dd()ddd ()dd()xtt a b t t a - x b - x x xka xb xtii a bababxka xb xtaxktbxktaxbxxktaxxb+ = =+= H CY 2axkt ab-x= 2222002(2) 2A P 0 02d(211222dd)dxtt a t t a - x x xkt(a - x)ktaxka-xxta= =34: 291 ,2()2()2()KCH CHO g CH g CO g=+99 H /Y s
8、QY S L1B B HW =9 Q UTQ L1Bk Q=)Qb ! Y S 34000000 0 012()2()2()000211 1 1 122ppCH CHO g CH g CO gtptt p p p pppp pppdpkdtktp p p p p ps=+=+ = 999Q Q Q UUTL L1B a )QQ qZ i Q )Qb )Q V ?Q 32333A B C P ABC2A B P A B3A P Arkrkrk+ + =+ =33333323300A + B + C Pt=0 a b c 0t=t (a-x) (b-x) (c-x) xd()()()d( ) (
9、= = )dd()dd()12( )xtxka xb xc xtka x abcktxktaxxktaxax=+= 32211 12( )ktax a=323222111232213 724 8()1111332: 1521abctkaxkt a-x attkattt=:)Q +a TmL| q aQ i HW1“ T a q i HW a Q S i ZQ1 %+a ,)QQ qZQ iC Q qQ i1n ,)Q V bQ bQ HQ9 V Q q %8b4rV ib00000A P0 0 = - ddd d xttatt ax xxktxktxkt=101021232xtkatk=,)Q +a L1“a i HWa Q Si1111/21112()13nnnnktaxtAa=a )Q+a q i HWa L1“a BaQ) EasE Q) L B“ Q iYj U T/ k |F Y U e) Q q s T9 Lb sY/ Z TTm T mBL5QM) sE ae) 211ln ()ax t t tax ax 2asE Q) A,0AAAAAAAnA Pt =0 c 0t =t c xdddln ln ln lnddln lndnncrkctcnctcct= = =+TmVL| q p
