1、 8O y ! “(No.2001-11)l :2002-06-19, :2002-09-16 ) 1“唐欣昀 张 明 赵海泉 周隆义 陈晓琳( jD , In. V,Hq/ P M( = b V1 n) , PV1 =V;A , V1/V = b s 。(7) T, V2 8,P1=101.33kPa H, V1=8,yNV1/V2 = b s 。 b b , 88M, V1/V2=1; b b , V1/V21; b ,V1/V2=0, P2=0, b s0。m2 )Q = 1“1 B , 2 b (100%), 3 9 1.3 ) 89 1“ 89 P V:s p V U6 :5 Mi
2、b (L ( ) Fs,y7:P =Pw +Pa (8)TPw、PasYV U b s。i b HPW 6, V 96,7 。D 7 Z(7)sYPw-TPa-T1“,Vm2 Vn1“sY wLL,Z(3)(7)“Q B Y L。yNEVPwPaPT1“。Vm VnP-T1“ BM wL, V AntoineZ :152003 M30 (3) 3YlogP =-A/ (T +C)+B (9)5:T =-A/ (logP-B)-C (10)2 9 ZE2.1 AntoineZ“ 7Z(7)V1/V2=1 ( =100% b ), P1=101.33kPa, T1=293K,/ ZE V p“ A
3、、B、C。D7 B(80120S =) H Pw,Z(7) pB H b = H Pa, Z(8) p H9 P,:T1P1=Pw1+Pa1 T2 P2 =Pw2 +Pa2 T3 P3=Pw3 +Pa380120S = (3FTP V) Z(10),1A、 B、C Z, p“ A、B、C。 V p b = f /(V1/V2 =0.75, V1/V2=0.5, V1/V2=0.25, V1/V2=0)AntoineZ“ 。2.2 ) = b H9 2.19 ) = b H AntoineZ“ , b = ,Z(10)9 /。3 T) 3.1 AntoineZ“ V1 HP、 Pw、 PaT/K
4、 P/kPa Pw/kPa Pa/kPa353.15 167.378 47.356 120.022373.15 228.142 101.322 126.820393.15 332.162 198.545 133.617V2 AntoineZ“ Vb = (%) A B C1 100 +3085.6 +7.3284 +249.292 75 +517.83 +0.22079 -622.433 50 +1301.9 -1.3410 -738.624 25 +26494 -15.612 -1866.65 0 +1639.8 +7.0481 -47.791:AntoineZ:T =-A b: L= =
5、V (kPa)+101.33kPa d ;7“ b nv n2 3”5 Y LMQ,y P-T1“ Z, 67 y 6(m2),7 b P-T1“LZ。D2 51 ) = M。1 V2 D , Vn bM b M Hq/, D 1。 tD 9 ZE,V-%s, VtD ( I n b sy,7 I n b s ny 。D2 , V10 1bfin-2 =B b Hq H(V1/V2 =0.5)105。N H ) = L= 10 6.896 ( y0)+101.33 (v ) =170.29 kPa,VNh B b s n7 3sPa,Pw =170.29-101.330.5 =120.24 k
6、Pa。VD7 V15“ %AntoineZ, VN /B 105。|9 PB H, b VE 1$F ,Ta 6,V7PaPwTw,Ta =Tw,Tw105。 ZE9 (V13Z), 0MHq/101.2。A I n b s ny 。ZE 80 120 y AntoineZ,NS = l,NS v,+Y = b v80/Hq H, 1 L=。Clausius-ClapeyronZ、ol9 X 8Z:s p,s ) 8 1“,9 = b HAntoineZ, V(P)9 (T)ZE, )A b b n d。 ID1qv,vI. 3(=).:, 1987.251.2S , , + I. 3 L(=).:, 1989.100 101.3 ,0 d, I. j 3 L/ .:S j, 1996.48 49.4 i. 3.:, 1993.208.5 PGerhardtI.0 v 3“ 3 ir. Y% )ZE m.0 :0 v,1989.595.6 V. , H.F.W 5, U. S X . zr. .:, 1983.1 23,125 130.7$ i, L R,z i ,I.V. 2: S/ , 1979.2,139 2,142.172003 M30 (3) 3Y
