1、 Safety Data Sheet according to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015 Print Date: May 12, 2017 Page 1 of 10 Section 1. Identification of the substance/ mixture and of the company/ undertaking 1.1 Product identifier Product name: POLYL
2、AC This safety data sheet pertains to the following products: PA-7571.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Mixture used for the production of molded plastic articles 1.3 Details of the supplier of the Safety Data Sheet Supplier: Ch
3、i Mei Corporation Address: 59-1, San Chia, Jen Te Village Tainan County Taiwan R.O.C. Telephone: +886 6 2663000 Ext.1347 Email: .tw - 1.4 Emergency telephone number Emergency telephone : +886 6 2663000 Ext. 2501 Section 2. Hazards identification 2.1 Classification of the substance or mixture Classif
4、ication according to Directive 67/548/EEC or 1999/45/EC: Not classified as hazardous (polymeric state) Classification according to Regulation (EC) N 1272/2008 (CLP): Not classified as hazardous (polymeric state) 2.2 Label elements Not labelled as hazardous 2.3 Other hazards vPvB/PBT assessment: not
5、available Section 3. Composition/information on ingredients 3.1 Composition of the substance/ preparation Substance or Preparation Substance Content CAS Name content 9003-56-9 Acrylonitrile-Butadiene-Styrene copolymer 98 % - Additives 2 % Impurities Contributing to Hazard None Safety Data Sheet acco
6、rding to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 2 of 10 3.2 Additional information: Reach Info: Pre-registration No. Registration No. Acrylonitrile 05-2117149456-38-0000 01-2119474195-34-0045 Styrene 05-2117149462-45-0000 01-211945
7、7861-32-0006 01-2119457861-32-0007 01-2119457861-32-0057 01-2119457861-32-0065 01-2119457861-32-0081 Buta-1,3-diene 05-2117149467-35-0000 01-2119471988-16-0044 3.3 For full text of R- and H-phrases: see section 16 Section 4. First-aid measures 4.1 Description of first aid measures General notes: Rem
8、ove affected persons from the danger area, at the same time ensuring your own safety. Remove all contaminated clothing immediately Following inhalation: In case of gases evolving from melted resin, move subject to fresh air. Treat symptomatically Following skin contact: In case of pellets or powder,
9、 wash with water. In case of smelt, wash affected skin area and clothing with plenty of (soap and) water. Seek medical advice Following eye contact: In case of pellets or powder, flush with plenty of water for at least 15 minutes. Seek medical advice if any dust particles still remain. In case of ga
10、ses evolving from melted resin of high temperature, flush with plenty of water for at least 15 minutes. Seek medical advice if necessary Following ingestion: Induce vomiting. Rinse mouth with water. Seek medical advice if necessary Self-protection of the first aider: - 4.2 Most important symptoms &
11、effects both acute & delayed Dust: Skin irritation, eye irritations and redness 4.3 Indication of any immediate medical attention and special treatment needed: - Treat symptomatically. (Decontamination, vital functions) Section 5. Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing
12、 agents: Water, foam, dry chemical powder For safety reasons unsuitable extinguishing agents: - Print Date: May 12, 2017 Safety Data Sheet according to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 3 of 10 5.2 Special hazards arising from
13、 the substance or mixture: - 5.3 Advice for firefighters Protective equipment: Self-contained breathing apparatus Further measures: - 5.4 Additional information: - Section 6. Accidental release measures 6.1 Personal precautions, protective equipment & emergency procedures Pellets or powder remained
14、on ground may cause slipping Wear protective equipment Ensure adequate ventilation Keep away from ignition sources Keep unprotected persons away 6.2 Environmental precautions Gather pellets and powder thoroughly to avoid birds or fishes taking from draining water. Do not allow product to reach sewag
15、e system or water bodies. Inform respective authorities in case product reaches water, sewage system or soil 6.3 Methods and material for containment and cleaning up Recovery if not contaminated or disposal 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8
16、 for information on personal protection equipment. Section 7. Handling and storage 7.1 Precautions for safe handling Protective measures: - Measures to prevent fire: Prevent from fire around handling area Measures to prevent aerosol and dust generation: maintain good housekeeping standards to preven
17、t accumulation of dust. To avoid dust explosion resulting from the existence of powder, electrostatics eliminators and grounding should be fixed to such equipment as air transferring pipes, bag filters and hoppers. Use electrically conductive filters for bag filters. Measures to protect the environm
18、ent: - Advice on general occupational hygiene: - Print Date: May 12, 2017 Safety Data Sheet according to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 4 of 10 7.2 Conditions for safe storage, including any incompatibilities Technical meas
19、ures and storage conditions: Keep the material at a cool dry place. Protect from direct sunlight, rain and violent temperature fluctuation. Fire is inhibited around storage area. Requirements for storage rooms and vessels: - Suitable materials and coating: - Unsuitable materials or coatings: - Furth
20、er information on storage conditions: - 7.3 Specific end use(s) Recommendations: - Section 8. Exposure controls/personal protection 8.1 Control parameters Exposure Limits:None established 8.2 Exposure control Appropriate engineering controls: Install eyes washer and shower in the place of operation.
21、 Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits Personal protection: - Respiratory protection: Wear masks for cleaning molding machines - Hand protection: Heat-insulting gloves when handling molten form - Eye protection: Wear safety glasses for general pu
22、rpose. Wear chemical goggles for cleaning molding machines - Skin and body protection: Gloves necessary for handling melted resin - Hygiene measures: Wash hands after handling 8.3 Environmental exposure controls Product related measures to prevent exposure: None specific Instruction measures to prev
23、ent exposure: None specific Organizational measures to prevent exposure: None specific Technical measures to prevent exposure: None specific Environmental exposure controls: Do not allow product to reach sewage system or water bodies Print Date: May 12, 2017 Safety Data Sheet according to EU 1907/20
24、06 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 5 of 10 Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state: solid, granulate Odour Odourless or negligible Colour Natural or
25、off-white Odour threshold None pH Not applicable Melting point / freezing point not determined Initial boiling point and boiling range Not applicable Flash point 404 C Evaporation rate Not applicable Flammability (solid, gas) Not available Upper/lower flammability or explosive limits 45 g/m (open cu
26、p, powder) Vapour pressure Not applicable Vapour density Not applicable Relative density (H2O=1) 1.03 - 1.10 g/cm Bulk density Not available Solubility(ies) Not soluble Partition coefficient (n-octanol/water) Not available Auto-ignition temperature 466 C Decomposition temperature 300 C Viscosity Not
27、 applicable Explosive properties Not explosive Oxidizing properties Not oxidizing 9.2 Other safety information: - Section 10. Stability and reactivity 10.1 Reactivity: Non-reactive under normal handling and storage conditions 10.2 Chemical stability: Stable under normal handling and storage conditio
28、ns 10.3 Possible hazardous reaction: - 10.4 Conditions to avoid: Avoid excessive heat, flames and all sources of ignition 10.5 Incompatible materials: not applicable 10.6 Hazardous decomposition products: not applicable Print Date: May 12, 2017 Safety Data Sheet according to EU 1907/2006 (REACH) and
29、 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 6 of 10 Section 11. Toxicological information 11.1 Information on toxicological effects Toxicological effects: - Acute toxicity (oral): Lack of data. - Acute toxicity (dermal): Lack of data. - Acute toxicity (inhalat
30、ive): Lack of data. - Skin corrosion/irritation: Lack of data. May cause irritations. - Eye damage/irritation: Lack of data. May cause irritations. - Sensitisation to the respiratory tract: Lack of data. Not to be expected - Skin sensitisation: Lack of data. Not to be expected - Germ cell mutagenici
31、ty/Genotoxicity: Lack of data. Not to be expected - Carcinogenicity: Lack of data. Not to be expected - Reproductive toxicity: Lack of data. Not to be expected - Effects on or via lactation: Lack of data. - Specific target organ toxicity (single exposure): Lack of data. - Dusts: Irritating to eyes,
32、respiratory system and skin. - Specific target organ toxicity (repeated exposure): Lack of data. Other information Styrene: - Harmful if inhaled. Causes damage to organs through prolonged or repeated exposure. - lung damages - May be fatal if swallowed and enters airways. - Causes serious eye irrita
33、tion. Causes skin irritation. Acrylonitrile: - Toxic by inhalation, in contact with skin and if swallowed. - May cause cancer. Suspected of damaging the unborn child. - Causes skin irritation. May cause an allergic skin reaction. Causes serious eye - damage. 1,3-Butadiene: - May cause cancer. May ca
34、use genetic defects. Symptoms - Dust:Can cause skin, eye and respiratory tract irritation. - The melted product can cause severe burns. - Thermal treatment, Processing: - Irritating to eyes, respiratory system and skin. - In case of ingestion: Swallowing may cause gastrointestinal irritation and pai
35、n of guts. Print Date: May 12, 2017 Safety Data Sheet according to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 7 of 10 Section 12. Ecological information 12.1 Toxicity Method Results Reference Short-term aquatic toxicity Based on availa
36、ble data on the constituents the classification criteria are not met LC(50) mixture = 5.78 mg/l (additivity and summation method, toxicity information available for 92,5 % of the mixture) Long-term aquatic toxicity Based on available data on the constituents the classification criteria are met and t
37、he mixture is therefore classified as Aquatic Chronic 1 NOEC mixture = 0.0079 mg/l (additivity and summation method, toxicity information available for 78 % of the mixture) 12.2 Persistence and degradability Further details: - Biodegradation: Product is not readily biodegradable. - The product is li
38、kely to persist in the environment. Effects in sewage plants: - In sewage treatment plants it may be separated mechanically. 12.3 Bioaccumulative potential To avoid bioaccumulation plastics should not be disposed in the sea or in other water environments. 12.4 Mobility in soil no data available 12.5
39、 Results PBT & vPvB assessment According to the revised Annex XIII of regulation (EC) 1907/2006 and (EC) 253/2011: No information available on the product as such 12.5 Other adverse effects: General information: Do not allow to enter into ground-water, surface water or drains. 12.7 Additional inform
40、ation: - Section 13. Disposal considerations 13.1 Waste treatment methods Product / Packaging disposal: Dispose in accordance with the current local regulations. Waste codes according to European Waste Catalogue: - Waste treatment-relevant information: Inadequate incineration may generate toxic gase
41、s such as CO, HCN, AN and SM Sewage disposal-relevant information: - Other disposal recommendations: - Print Date: May 12, 2017 Safety Data Sheet according to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 8 of 10 Section 14. Transport inf
42、ormation ADR/RID 14.1 UN number Not applicable 14.2 UN proper shipping name Proper Shipping Name: NOT REGULATED 14.3 Transport hazard class(es) Not applicable 14.4 Packing Group Not applicable 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special pr
43、ecautions for user Special Provisions: no data available Hazard identification No:no data available ADNR / ADN 14.1 UN number Not applicable 14.2 UN proper shipping name Proper Shipping Name: NOT REGULATED 14.3 Transport hazard class(es) Not applicable 14.4 Packing Group Not applicable 14.5 Environm
44、ental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user no data available IMDG 14.1 UN number Not applicable 14.2 UN proper shipping name Proper Shipping Name: NOT REGULATED 14.3 Transport hazard class(es) Not applicable 14.4 Packing Group Not
45、 applicable 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user EMS Number: Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable ICAO/IATA 14.1 UN number Not applicable Pr
46、int Date: May 12, 2017 Safety Data Sheet according to EU 1907/2006 (REACH) and 1272/2008 (CLP) Product name: POLYLAC ABS Version 1 Revision Date: June 1,2015Page 9 of 10 14.2 UN proper shipping name Proper Shipping Name: NOT REGULATED 14.3 Transport hazard class(es) Not applicable 14.4 Packing Group
47、 Not applicable 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user no data available Section 15. Regulatory information 15.1 Safety, health and environmental regulations /legislation specific for the substance or mixture Auth
48、orization and / or restrictions on use: None Other EU regulations: The following substances are under European Seveso regulation: Substance Seveso category Other Seveso categories Seveso concentrations Categories Acrylonitrile 2 9ii 7b 10 % C 20 % 2 Buta-1,3-diene 0 8 - - Styrene 6 - C 12,5 % - Othe
49、r national regulations: - 15.2 Chemical Safety Assessment For this substance a chemical safety assessment is not yet required. Section 16. Other information 16.1 Indication of changes Version 1: First issue according to Regulations (EC) 1907/2006 (REACH) & 1272/2008 (CLP) 16.2 Abbreviations and acronyms AGS Ausschuss fr Gefahrstoffe LoW List of Waste AF Assessment Factor MARPOL MARine POLlution BCF BioConcentration Factor MIE Minimum Ignition Energy CAS Chemical Abstract Service NEC European Commission number CMR Carcinogenic, Mutage
