1、常用化学品名称缩写一览%de% diasteromeric excess %ee% enantiomeric excess 1,5-HD 1,5-hexadienyl 9-BBN 9-borabicyclo3.3.1nonane Ac Acetyl acac Acetylacetonate AIBN Azo-bis-isobutryonitrile aq. Aqueous BINAP (2R,3S)-2,2-bis (diphenylphosphino)-1,1-binaphthyl Bn Benzyl BOC t-butoxycarbonyl Bpy(Bipy) 2,2-bipyridyl
2、Bu n-butyl Bz Benzoyl c- Cyclo CAM Carboxamidomethyl CAN Ceric ammonium nitrate Cat. Catalytic CBz Carbobenzyloxy Chirald (2S,3R)-(+)-4-dimethylamino-1,2-diphenyl-3-methylbutan-2-ol COD 1,5-Cylcooctadienyl COT 1,3,5-cyclooctatrienyl Cp Cyclopentadienyl CSA 10-camphorsulfonic acid CTAB Cetyltrimethyl
3、ammonium bromide Cy Cyclohexyl DABCO 1,4-diazabicyclo2.2.2octane dba Dibenzylidene acetone DBE 1,2-dibromoethane DBN 1,8-diazabicyclo5.4.0undec-7-ene DBU 1,5-diazabicyclo4.3.0non-5-ene DCC 1,3-dicyclohexylcarbodiimide DCE 1,2-dichloroethane DDQ 2,3-dichloro-5,6-dicyano-1,4-benzoquinone DEA Diethylam
4、ine DEAD Diethyl azodicarboxylate Dibal-H Diisobutylaluminum hydride diphos(dppe)1,2-bis (diphenylphosphino)ethane diphos4(dppb1,4-bis (diphenylphosphino)butane DMAP 4-dimethylaminopyridine DME dimethoxyethane DMF N,N-dimethylformamide dppf bis (diphenylphosphino)ferrocene dppp 1,3-bis (diphenylphos
5、phino)propane dvb Divinylbenzene e- Electrolysis EDA (en) ethylenediamine EDTA Ethylenediaminetetraacetic acid EE 1-ethoxyethyl Et Ethyl FMN Flavin mononucleotide fod Tris-(6,6,7,7,8,8,8)-heptafluoro-2,2-dimethyl-3,5-octanedionato Fp flash point OR Cyclopentadienyl-bis -carbonyl iron FVP Flash vacuu
6、m pyrolysis h hours HMPA Hexamethylphosphoramide HMPT Hexamethylphosphorus triamide hv Irradiation with light iPr isopropyl LAH Lithium aluminum hydride LDA Lithium diisopropylamide LHMDS Lithium hexamethyldisilazide LTBA Lithium tri-tert-butoxyaluminum hydride mCPBA meta-cholorperoxybenzoic acid Me
7、 Methyl MEM b-methoxyethoxymethyl Mes Mesityl Min Minute MOM methoxymethyl Ms Methanesulfonyl MS Molecular sieves (3 or 4 ?) MTM Methylthiomethyl Naphth Naphthyl NBD Norbornadiene NBS N-Bromosuccinimide NCS N-chlorosuccinimide Ni(R) Raney Nickel NMO N-methyl morpholine-n-oxide PCC Pyridinium chloroc
8、hromate PDC Pyridinium dichromate PEG Polyethylene glycol Ph Phenyl PhH Benzene PhMe Toluene Phth Phthaloyl Pip Piperidyl Pr n-propyl Py Pyridine quant. quantitative yield Red-Al (MeOCH2CH2O)AlH2Na sBu sec-butyl sBuLi sec-butyllithium Siamyl Diisoamyl TASF Tris(diethylamino)sulfonium difluorotrimeth
9、yl silicate TBAF Tetrabutylammonium fluoride TBDMS,TBS t-butyldimethylsilyl TBHP t-butylhydroperoxide t-Bu Tert-butyl TEBA Triethylbenzylammonium TEMPO Tetramethylpiperdinyloxy free radical Tf or OTf Triflate TFA Trifluoroacetic acid TFAA Trifluoroacetic anhydride THF Tetrahydrofuran THP Tetrahydropyranyl TMEDA Tetramethylethylenediamine TMP 2,2,6,6-tetramethylpiperidine TMS Trimethylsilyl Tol Tolyl Tr Trityl TRIS Triisopropylphenylsulfonyl Ts(Tos) Tosyl (p-toluenesulfonyl)
