1、The MSDS format adheres to U.S. standards and regulatoryrequirements and may not meet regulatory requirements inother countries.MSDS规格遵照美国标准及规范要求，但并不一定符合其他国家的规范要求。This information is based upon technical informationbelieved to be reliable. It is subject to revision asadditional knowledge and experie
2、nce are gained.此资料依据被认为是可靠的技术资料汇编而成，但可随新的知识及经验的增长而随时修订。AMMONIUM MOLYBDATE 钼酸铵CF0236 Revised 16-OCT-1999 Printed 17-MAY-2000CF0236 1999年10月16 日修订 2000年5月17 日印制CHEMICAL PRODUCT/COMPANY IDENTIFICATION 化学品/公司识别Material Identification产品识别Corporate MSDS Number : DU006246DSPC MSDS No. : A13CAS Number : 131
3、06-76-8Formula : N2H8MO04Molecular Weight : 196.04协会MSDS编号 :DU006246CAS号 :13106-76-8分子式 :N2H8MO04分子量 :196.04Tradenames and Synonyms商品名及别名AMMONIUM PARAMOLYBDATEDIAMMONIUM MOLYBDATE仲钼酸铵钼酸二铵Company Identification公司识别MANUFACTURER/DISTRIBUTORBAKER; FISHER; KODAK; EM SCIENCE;ACROS ORGANICS生产商/分销商BAKER公司；F
4、ISHER公司；KODAK；EM SCIENCE公司；ACROS公司；ORGANICS公司；PHONE NUMBERSTransport Emergency : CHEMTREC: 1-800-424-9300Medical Emergency : 1-800-441-3637电话号码运输应急：CHEMTREC: 1-800-424-9300医疗应急：1-800-441-3637COMPOSITION/INFORMATION ON INGREDIENTS 组成/组份资料Components成份Material CAS Number %AMMONIUM MOLYBDATE 13106-76-8
5、99-100ORAMMONIUM MOLYBDATE, TETRAHYDRATE 12027-67-7 99-100ORAMMONIUM PARA-MOLYBDATE TETRAHYDRATE 12054-85-2 99-100材料 CAS号 %钼酸铵 13106-76-8 99-100或 钼酸铵四水合物 12027-67-7 99-100或：仲钼酸铵四水合物 12054-85-2 99-100HAZARDS IDENTIFICATION 危险识别Potential Health Effects对健康可能产生的影响Poisoning may affect the blood, liver, a
6、nd kidneys. Atincreased risk from exposure: Persons with pre-existingrespiratory, kidney, or blood disorders or gout.中毒可能会影响血液、肝脏及肾脏、接触后危险性增大的有：原先患有呼吸、肾脏、或血液不正常或痛风的病人。May be excreted in breast milk. The body levels of copper,sulfur, and zinc may have an effect on the toxicity.(Based on information o
7、n soluble molybdenum compounds).可在乳液中排泄出应分开体内铜、硫及锌的含量高低会对其毒性产生影响。（根据可溶性钼化合物的资料）INHALATION吸入May cause irritation of the respiratory tract.可引起上呼吸道刺激SKIN CONTACT皮肤接触May cause irritation. Chronic: Among chemists handlingsolutions of molubdenum and tungsten, there was a highincidence of gout.可引起刺激、漫性：在接触
8、到钼及钨的溶液的化工人员中，有较高的痛风发生率。EYE CONTACT眼接触May cause irritation.可引起刺激INGESTION摄入May be harmful if swallowed.若吞咽下则会是有害的。Carcinogenicity Information致癌性资料None of the components present in this material at concentrationsequal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIHas a carcinogen.被IARC
9、, NTP, OSHA或ACGIH列为致癌的，在此物质的成份中没有一个基浓度是等于或大于 0.1%的。FIRST AID MEASURES 急救措施First Aid急救INHALATION吸入If inhaled, remove to fresh air. If not breathing, giveartificial respiration. If breathing is difficult, give oxygen.Call a physician.若已吸入则移至新鲜空气处，若已停止呼吸则施以人工呼吸，若呼吸困难则输以氧气，请来医生。SKIN CONTACT皮肤接触Flush ski
10、n with water after contact. Wash contaminated clothingbefore reuse.接触后用水冲洗，在衣服再次穿用前要清洗干净。EYE CONTACT眼接触In case of contact, immediately flush eyes with plenty of waterfor at least 15 minutes. Call a physician.万一接触到后，立即用大量的水至少冲洗15分钟，请来医生。INGESTION摄入If swallowed, do not induce vomiting. Immediately giv
11、e 2 glassesof water. Never give anything by mouth to an unconscious person.Call a physician.若已吞咽下去，不要设法呕吐，立即喝二大杯水，千万别给已失去知觉的人从嘴中喂食任何东西，请来医生。Notes to Physicians提示医生Activated charcoal mixture may be administered. To prepareactivated charcoal mixture, suspend 50 grams activated charcoal in400 mL water
12、and mix thoroughly. Administer 5 mL/kg, or 350 mLfor an average adult.可服用活性碳混合物，制备活性碳混合物方法为：将50克活性碳悬浮于400 mL水中并混合均匀，服用量为5 mL/kg或对一般成年人350 mL。FIRE FIGHTING MEASURES 消防措施Flammable Properties易燃性质Not a fire or explosion hazard.无着火或爆炸危险Hazardous gases/vapors produced in fire are ammonia.着火时产生的有害气体/蒸气为氨Ex
13、tinguishing Media灭火介质Use media appropriate for surrounding material.采用适合于周边物质的灭火介质。Fire Fighting Instructions消防须知Keep personnel removed and upwind of fire. Wear self-containedbreathing apparatus. Wear full protective equipment.将人员撤至着火的上风处，戴上自背式呼吸器，穿戴齐全防护设备。Move containers from fire area if it can be
14、 done withoutrisk. Closed containers exposed to heat may explode.若可以做到无危险的话，将容器搬离着火区域，密封的容器受热后，可能会发生爆炸。ACCIDENTAL RELEASE MEASURES 事故消除措施Safeguards (Personnel)防护（人员）NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)sections before proceeding with clean-up. Use appropriatePERSONAL PROTECTIV
15、E EQUIPMENT during clean-up.注：在清理干净之前，参阅“消防措施”及“处理（人员）”有关章节，在清理时，使用适当的“人员防护设施”。Accidental Release Measures事故消除措施With clean shovel, carefully place material into clean,dry container and cover. Remove from area. Flush spillarea with water.用干净的铲子，小心将物质铲入洗净、干燥的容器中并盖上盖子并搬走，用水冲洗洒出区域。HANDLING AND STORAGE 运
16、输及贮藏Handling (Personnel)运输（人员）Avoid breathing dust. Avoid contact with eyes, skin, or clothing.Wash thoroughly after handling. Wash clothing after use.避免吸入其尘粒，避免其与眼、皮肤及衣服接触，运输后要彻底洗净，穿过的衣服要洗净。Handling (Physical Aspects)运输（周边环境）Avoid dust generation. Keep away from heat, sparks and flames.避免产生尘粒，避免靠近热
17、、火花及火焰。Storage贮藏Do not mix with strong acids. Store in a well ventilated place.Keep container tightly closed.不要与强酸混合堆放，贮藏于通风良好之处，保持容器密闭。Store in a dry place.贮藏于干燥之处。EXPOSURE CONTROLS/PERSONAL PROTECTION 接触控制/人员防护Engineering Controls工程控制Keep container tightly closed. Use sufficient ventilation to kee
18、pemployee exposure below recommended limits.保持容器密闭，通风良好，使人员接触到的是低于推荐的极限。Personal Protective Equipment人员防护设施EYE/FACE PROTECTION眼/脸防护Wear coverall chemical splash goggles when the possibility existsfor eye or face contact from airborne material.当眼及脸当有可能接触到空气中的该物质时，要戴上封闭式化学防溅护目镜。RESPIRATOR呼吸器A NIOSH ap
19、proved air purifying respirator with particulatecartridge or canister may be permissible under certaincircumstances where airborne concentrations are expected to exceedexposure limits. Protection provided by air-purifying respiratorsis limited. Use a NIOSH approved positive pressure air-suppliedresp
20、irator if there is any potential for an uncontrolled release,exposure levels are not known, or any other circumstances whereair-purifying respirators may not provide adequate protection.在空气中浓度可能超过接触极限的某些场合，允许使用为NIOSH批准的带活性碳过滤器或滤毒筒的空气净化呼吸器，但空气净化呼吸器所提供的防护是有限的，若有下列可能则要用NIOSH批准的正压供气 呼吸器：无法控制的泄漏，接触浓度未知，或
21、其它的空气净化呼吸器不能提供足够保护任何场合。PROTECTIVE CLOTHING防护服装Wear impervious clothing, such as gloves, apron, boots, or wholebodysuit as appropriate.穿上不透水的服装，例如手套、围裙、靴子、或连衣裤。Recommended glove material: No vendor recommendation on materialof construction for protective clothing.推荐手套材料：对防护服装的材质，卖主并未推荐。# Exposure Gui
22、delines# 接触准则Exposure LimitsAMMONIUM MOLYBDATEPEL (OSHA) : Particulates (Not Otherwise Regulated)15 mg/m3, 8 Hr. TWA, total dust5 mg/m3, 8 Hr. TWA, respirable dust接触最大浓度钼酸铵PEL (OSHA) : 颗粒（没有另外规定）15 mg/m3, 8 小时暂时工作区，总尘量5 mg/m3, 8小时工作区，可吸入尘量Other Applicable Exposure Limits其它适用接触最大浓度AMMONIUM MOLYBDATE,
23、 TETRAHYDRATEPEL (OSHA) : 5 mg/m3, and soluble compounds, as MoInsoluble compounds: 15 mg/m3, TotalDust as 8 Hr TWAsTLV (ACGIH) : 10 mg/m3, insoluble compounds, as Mo5 mg/m3, soluble compounds as Mo8 Hr TWAsNotice of Intended Changes (1999)Elemental/Metal and insoluble compounds10 mg/m3 (Inhalable f
24、raction)3 mg/m3 (Respirable fraction)0.5 mg/m3 (Soluble compounds), A3AEL * (DuPont) : None Established钼酸铵，如水合物PEL (OSHA) : 5 mg/m3,及可溶性化合物，钼的不溶性化合物：15 mg/m3, 总尘量8小时暂时工作区TLV (ACGIH) : 10 mg/m3, 不溶性化合物，钼5 mg/m3,可溶性化合物钼8小时暂时工作区变更通知（1999）元素/金属及不溶化合物10 mg/m3 (可吸入部分)3 mg/m3 (可呼吸部分)0.5 mg/m3 (可溶化合物), A3AE
25、L * (杜邦 ) : 尚未建立* AEL is DuPonts Acceptable Exposure Limit. Where governmentallyimposed occupational exposure limits which are lower than the AELare in effect, such limits shall take precedence.*AEL为杜邦公司可接受的接触最大浓度，若政府规定的职业接触最大浓度低于AEL，则采用最大浓度。PHYSICAL AND CHEMICAL PROPERTIES 物理及化学性能Physical Data物理数据B
26、oiling Point : 190 C (374 F) DecomposesVapor Density : 2.5 (Air = 1)Melting Point : 90 C (194 F) Hydrates (loses water)190 C (374 F) 760 mm/HgSolubility in Water : 10 WT% (Appreciable) 43% (cold)pH : 5.0-5.5 5% solutionOdor : OdorlessForm : Solid (crystals)Color : White to yellow-greenSpecific Gravi
27、ty : 2.2-2.5 (Water=1)沸点 : 190(374) 分解蒸气密度 ：2.5 (空气 = 1)溶点 ：90 (194) 颗粒 (没有另外规定)190 (374) 760 mm/Hg水中溶解度 ：10 重量% (明显) 43% (冷)PH ：5.0-5.5 5%溶液气味 ：无气味形态 ：固态（结晶）颜色 ：白至黄绿色比重 ：2.2-2.5 (水=1)Solvent solubility: Soluble in acids, alkalis, ammoniumchloride solution. Insoluble in alcohol.溶剂溶解性：溶于酸、碱及铵盐及氯化物溶液中
28、，不溶于酒精。STABILITY AND REACTIVITY 稳定性及反应性Chemical Stability化学稳定性Stable at normal temperatures and storage conditions.在常温贮藏条件下稳定Incompatibility with Other Materials与其它物质不相容性Incompatible with strong oxidizing agents, strong acids.与强氧化剂，强酸不相容。Decomposition分解性Decomposes with heat.遇热分解Hazardous gases/vapor
29、s produced are ammonia and oxides ofnitrogen.产生的危害气体/蒸气为氨及氮氧化物。Polymerization聚合性Polymerization will not occur.不会发生聚合TOXICOLOGICAL INFORMATION 毒物学资料Animal Data动物数据Ammonium Molybdate动物数据Oral LD50 (Rats) 3883 mg/kgIHL LC50 (Rats) 1930 mg/m3/4h口服LD50（白鼠）3883 mg/kgIHL LC50 (白鼠) 1930 mg/m3/4hAmmonium Moly
30、bdate Tetrahydrate钼酸铵四水合物Oral LD50 (Rats) 333 mg/kg口服LD50(白鼠) 333 mg/kgIngestion: In animals, large doses have caused dyspnea,anorexia, colic, trembling, and incoordination.Listlessness, anemia, and deformities of the forelegs werereported. There is a correlation between molybdenumconcentration in f
31、ood and incidences of elevated xanthineoxidase activity, bout and uricemia. In animals, molybdenummay interfere with copper metabolism.摄入：在动物身上，大剂量要引起呼吸困难、疼痛、发抖及共济失调，还有报导有：疲倦、贫血及前腿畸形，食物中钼的高的黄嘌呤氧化酶活性之间有相互关系，在动物身上，钼可能会干扰铜的新陈代 谢。DISPOSAL CONSIDERATIONS 废弃要点Waste Disposal废物处理Treatment, storage, transpor
32、tation, and disposal must be inaccordance with applicable Federal, State/Provincial, and Localregulations. Do not flush to surface water or sanitary sewersystem.处理、贮藏、运输及废弃须符合现行联邦、州/省及地方法规，不要冲洗入地面水及污水系统中。TRANSPORTATION INFORMATION 运输资料Shipping Information运输资料DOTProper Shipping Name : NON-REGULATEDDO
33、T正确运输名称： 没有规定REGULATORY INFORMATION 法规资料U.S. Federal Regulations美国联邦法规TSCA Inventory Status : Reported/Included.TSCA库存状况：已报导/已包括TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312第III条危险分类第311，312节Acute : YesChronic : YesFire : NoReactivity : NoPressure : No急性 ：是慢性 ：是着火 ：否反应性 ：否压力 ：无OTHER INFORMATION
34、 其它资料NFPA, NPCA-HMISNFPA, NPCA-HMISNPCA-HMIS RatingHealth : 1 (Chronic Health Effects)Flammability : 0Reactivity : 0NPCA-HMIS等级健康 ：1（慢性健康影响）易燃性 ：0反应性 ：0Personal Protection rating to be supplied by user depending on useconditions.个人防护等级视使用条件由用户提供。Additional Information附加资料Technical data, based on J.
35、T. Baker MSDS dated 1/4/94,Fisher Scientific MSDS dated 10/12/92, Eastman Kodak Co.MSDS dated 11/18/86, E. M. Science MSDS dated2/24/94; Acros Organics MSDS dated 1/12/96.技术数据根据1994年4月1 日的J. T. Baker公司MSDS，1992年12月10 日的Fisher科学公司MSDS， 1986年 11月18日的Eastman Kodak公司MSDS，1994年2月24日的E. M.公司MSDS， 1996年 12
36、月1日的Acros Organics公司MSDS。J. T. Baker Chemical Co.222 Red School LanePhillipsburg, NJ 08865(908) 859-2151 (Emergency)J. T. Baker 化学品公司.雷斯古路222号菲烈斯堡 NJ 08865(908) 859-2151 (应急 )Fisher Scientific Co.Chemical Division1 Reagent LaneFair Lawn, NJ 07410(201) 796-7100 (Technical & Emergency)Fisher科学公司化学品部雷琴
37、路1号弗厄浪，NJ 07410(201) 796-7100 (技术及应急 )Eastman Kodak Company343 State StreetRochester, NY 14650(716) 722-5151 (Emergency)(800) 225-5352 (Techical)(716) 458-4014 (In New York State)Eastman Kodak公司斯泰脱路343号罗彻斯特 NY 14650(716) 722-5151 (应急 )(800) 225-5352 (技术 )(716) 458-4014 (在纽约州 )E. M. Science480 Democr
38、at RoadGibbstown, NJ 08027609-354-9200E. M.赛因施公司台蒙克雷路480号吉布斯镇 NJ08027609-354-9200Acros OrganicsJanssen Pharmaceuticalaan 3a2440 Geel, Belgium800-ACROS-01Acros Organics公司杰逊法默修基公司3a2440奇尔比利时800-阿克罗斯-01-The data in this Material Safety Data Sheet relates only to thespecific material designated herein a
39、nd does not relate to use incombination with any other material or in any process.此物质安全数据表中的数据仅与此文中所指定的具体物质有关，而与其它任何物质混合使用无关。DuPontCorporate SHE Excellence CenterNemours Building - Room 2525Wilmington, DE 19898(302) 774-5723杜邦公司SHE人才中心Nemours Building-Room2525Wilmington, DE 19898(302) 774-5723# Indicates updated section.#表示修订过的章节End of MSDSMSDS结束
