1、 2016 2017 : 4 I ( ) II ( ) , 100 90 C 12 N 14 O 16 Na 23 S 32 Cl 35.5 I 36 12 36 1 ( ) A B C D 2 ( ) KClO 3 O 2 CaCO 3 CO 2 C=2CO Ba(OH) 2 8H 2 O NH 4 Cl C H 2 O(g)=CO H 2 Al A B C D 3 ( ) A B E 2 C H E 1 E 2D E1 E2 H 4 ( ) A HH 2 H 1 2H 3C H 1 Q 2 H 1 _H 2 (2)1 mol C 1 mol H 2 O(g) 1 mol CO(g) 1 m
2、ol H 2 (g) 131.5 kJ H _ 15 ( 2 14 )50 mL 0.50 mol L 1 50 mL 0.55 mol L 1 NaOH (1) _ (2) _ (3) _( ) (4) 60 mL 0.50 mol L 1 50 mL 0.55 mol L 1 NaOH _( ) _( ) (5) NaOH _( ) _ 16 ( 3 21 ) (1)1 mol N 2 (g) O 2 (g) NO(g) 68 kJ _ (2)1 L 1 mol/L 稀盐 酸跟 1 L 1 mol/L NaOH 57.3 kJ _ (3) 25 1.01 10 5 Pa 16 g S 14
3、8.5 kJ _ (4)N 2 (g) H 2 (g) 17 g NH 3 (g) 46.1 kJ _ (5)1 mol C 2 H 5 OH(l) CO 2 (g) H 2 O(l) 1 366.8 kJ _ (6) 44.8 L C 2 H 2 (g) O 2 (g) CO 2 (g) H 2 O(l) 2 598.8 kJ _ (7)24 g C(s) H 2 O(g) CO(g) H 2 (g) 262.6 kJ _ 17 (3 ) HH NH N N /kJ mol 1436 a 945 N2(g) 3H2(g)=2NH3(g) H 1 a =_ 18 (3 ) (H 2 ) (CO
4、) (C 8 H 18 ) (CH 4 ) H 2 (g) O 2 (g)=H 2 O(l) H 285.8 kJ mol 1CO(g) O 2 (g)=CO 2 (g) H 283.0 kJ mol 1 C 8 H 18 (l) O 2 (g)=8CO 2 (g) 9H 2 O(l) H 5 518 kJ mol 1CH 4 (g) 2O 2 (g)=CO 2 (g) 2H 2 O(l) H 890.3 kJ mol 1 H 2 CO C 8 H 18 CH 4 _ A H 2 (g) B CO(g) C C 8 H 18 (l) D CH 4 (g) 19 (5 ) (N 2 H 4 )
5、N 2 (g) 2O 2 (g)=2NO 2 (g) H 1 67.7 kJ mol 1 N 2 H 4 (g) O 2 (g)=N 2 (g) 2H 2 O(g) H 2 534 kJ mol 1 1 mol _ 2016 2017 : I ( ) II ( ) , 100 90 C 12 N 14 O 16 Na 23 S 32 Cl 35.5 I 36 12 3 36 1 2 3 4 5 6 7 8 9 10 11 12 II 64 7 64 13 ( 2 12 ) (1) _ (2) _ (3) _ (4) _ (5) _ _ _ 14 (6 ) (1) _ (2)H _ 15 ( 2
6、 14 ) (1) _ (2) _ (3) _( ) (4) _ _( ) (5) _( ) _ 16 ( 3 21 ) (1) _ (2) _ (3) _ (4) _ (5) _ (6) _ (7) _ 17 (3 ) a =_ 18 (3 ) _ 19 (5 ) _ 2016 2017 12 3 36 1 2 3 4 5 6 A B D D C C 7 8 9 10 11 12 D B A C B A 7 64 13 ( 2 12 ) (1) (2) (3) (5) 14 ( 3 6 ) (1) (2) 115 ( 2 14 ) (1) ( ) (2) (3) (4) (5) 16 ( 3
7、 21 ) (1)N 2 (g) O 2 (g)=2NO(g) H 68 kJ mol 1(2)HCl(aq) NaOH(aq)=NaCl(aq) H 2 O(l) H 57.3 kJ mol 1(3)S(s) O 2 (g)=SO 2 (g) H 148.5 kJ mol 1(4)N 2 (g) 3H 2 (g)=2NH 3 (g) H 92.2 kJ/mol (5)C 2 H 5 OH(l) 3O 2 (g)=2CO 2 (g) 3H 2 O(l) H 1 366.8 kJ/mol (6)2C 2 H 2 (g) 5O 2 (g)=4CO 2 (g) 2H 2 O(l) H 2 598.8 kJ/mol (7)C(s) H 2 O(g)=CO(g) H 2 (g) H 131.3 kJ/mol 17 (3 ) 391 18 (3 ) B 19 (5 ) N2H4(g) NO2(g)=N2(g) 2H2O(g) H 567.85 kJ/mol
