1、 2 (90 100 ) ( 15 2 30 ) 1 46302402 ( B ) A B C D 2 46302403 ( B ) A B KMnO4 C CnH2n 2 D KMnO4 H2SO4 B 3 O2 46302404 ( A ) A _ B C D CH y x CH y x (1 y 4x )O2 CO2 y 2x H2O CH y x y x 4 46302405 ( D ) A KMnO4 B NaOH C CH3CHCH2 D CH2Cl2 KMnO4 CH2Cl2 5 46302406 ( B ) A B C D A CaSO4 C MnO2 D B 6 463024
2、07 ( B ) B 7 46302408 ( B ) A B KMnO4 C D KMnO4 KMnO4 8 46302409 ( C ) A B C D C6H6 C2H2 w(H) 1 13 C3H6 C4H8 w(H) 1 7 9 1L 1.4L CO2 2.0L ( ) 46302410 ( B ) A B C D C1.4H4 4 4 10 46302411 ( D ) A B C CnH2n 2 CnH2n D A B CnH2n C 11 1 mol 246.4L( ) 4 46302412 ( A ) CnH2n 2 (n 2n 2 4 )mol (n 2n 2 4 )mol
3、 1 n 7 B C A 2 3 4 D 3 12 46302413 ( C ) A X Y B X Y C X Y D X Y X Y A B X Y C X Y D 13 C=C RCH= RCHO 46302414 ( D ) A B C D C=C 14 ag ag 46302415( D ) A H2 B CO C C6H12O6 D C12H22O11 2H2 O2= 2H2O,2H2O 2Na2O2=4NaOH O2 H2 Na2O2= 2CO O2= 2CO2,2CO2 2Na2O2=2Na2CO3 O2 CO Na2O2=Na2CO3 (CO)x(H2)y(x y 0) ag
4、 a g 15 X 46302416 ( D ) A X C8H8 B Y X Y C X D X H2 Z Z 4 X C8H8 X KMnO4 X H2 Z 2 ( 8 70 ) 16 (7 ) ( ) 46302417 (1) _ _ _ _( ) (2) B C (3) _NaOH _ (4) Cl2 NaOH A A Cl2 B NaOH Br2 NaOH ( ) 17 (10 ) 46302418 (1) ( ) _CaS 2H2O=Ca(OH)2 H2 _G_( ) a _( ) (2) A _ _ a B pH b B c _ B pH_ _ 2Br2 2 CHBr2 pH _
5、 2Br2 2HBr ( ) (1) CuSO4 H2S= H2SO4 pH pH 18 (14 ) 46302419 (1) a _ _ _Br2_ _ _ (2) b _ _ _ _ (3) c _ HBr _ (4) d AgNO3 _ _ _ _( ) (5) a _ _ _ _ _ _( ) _ NaOH _ (6) _ HBr _ 19 (10 ) A1 A2 1 mol H2 B A1 A2 1mol HCl C1 B C1 C2 B 83.7% A1 A2 B C1 C2 46302420 B 83.7% n(C) n(H) 83.7% 12 1 83.7% 1 3 7 C6H
6、14 20 (8 )(1) 4 H2 46302421 H2 1 3 _ _ _ _ H2 1 2 _ _ _ _ H2 _1 4_ (2) _ _ _ _ CH=CH2 _ _ _ _ (1) H2 2H2 CH2 CH2 3H2 4H2 H2 21 (7 ) A 84 46302422 (1)A (2)A _ _( (3) D1 D2 E1 E2 C E2 _ _ (1) 84 CnH2n 14n 84 n 6 C6H12 (2) (3) B C 2NaOH C2H5OH 2NaCl 2H2O C ( ) 22 (7 ) ( p xylene PX) 46302423 (1) PX (2)PX _ ( )_( ) (3) (DEHP) A PX 2 B _ _( ) 1 DEHP (4)F B a b FeCl3 c F NaHCO3 (1) (2) Cl2 Br2 HNO3 H2 B A 2 B D C CH2OH 1 B C DEHP (4)F FeCl3 NaHCO3 NaHCO3 CO2