1、1有机化学综合练习五解答一、1. H2NCH2CH2CH2CH2CH2CH2NH2 2. C2H5 NHC2H53. HCNO CH3CH3 N, N-4. CH3(CH2)16COOH 5. 6. 7. HOCCOOHCH2COOHCH2COOH8. 9.NCH3CH3 NHOO10. H2N NH2二、1、BDAC2、DBCA3、ABDC4、B5、B6、C7、A8、C9、ABC10、B三、1. COOC2H5COOC2H5 COOC2H5O22.COOC2H5 CC2H5 OHC2H53.OEtO O O4. N CH2PhOOPhCH2NH25. CH3CH COOHCl CH3CH C
2、OOHNH26. CH3CH2COOC2H5OZnBr CH3CH CH2COOHOH7. O O O8. DNHCH3CH3O9. NN NCH3CH3N2+Cl-10. N HHN NH2H2NH+11. OHCH2NH2O12. NCH3 CH3OH-+ NCH3 CH3313. NH2 I14. NHCNH CH3O CH315. CH3CH COOHOH C COCHOOOCCH3HCH316. OCHCOOC2H5COOC2H5OCH2COOH17. CH2COOHCOOH OOO18. OHCCH3OD D五、1. CH3COOC2H5 NaOC2H5 CH2OC OC2H5 C
3、2H5CCCH3OO-CH3 CO C2H5CH2 COOC2H5 OC CH2COOC2H5DC2H5O- CH3OCCHCOOC2H5NaOC2H5 CH3 Na HOAc+OC CH2COOC2H5CH32. COOEtCOOEt PhCOOOH COOEtCOOEtO4NaOC2H5 COOC2H5COOC2H5OCOOEtCOOEtO-C2H5OHCOOC2H5COOC2H5HO3. CNH2O Br2 CNHBrO OH-CNO Br NCOCH3OHNHCO CH3O4. OCH3 COH H+ OHCH3 COH OHCH3 COH+ +CH3 COHOHHOC2H5OH* C
4、2H5* CH3 COH2OHOC2H5* +DH2O OHCH3 CO* C2H5 DH+ OC OC2H5CH3+六、合成1. CH3 HNO3H2SO4 CH3NO2HClFe CH3NH2Br2CH3NH2Br BrNaNO2HCl CuCNCH3CNBr Br2. CH3 CCH3 O2 B( H)2 CH3 CCH3 CHCCH3O CH2 COOC2H5COOC2H5NaOC2H55CCH2CHCH3CH3 CCH3OCOOC2H5COOC2H5NaOC2H5 OO3. CH3 Cl2hv CH2Cl CH2 COOC2H5COOC2H5NaOC2H5CHCOOC2H5COOC2
5、H5 NaOC2H5CH2 C2H5ClCCOOC2H5COOC2H5 OH-C H2OC2H5H2 H+ CH2CC2H5HCOOH4. O CH3 OCH3CH(CH2)4COOHOHPhCOOOH H3O+ CH3O5. O KMnO4 H+H2O C2H5OHCOOHCOOH H+NaOC2H5COOC2H5COOC2H5 O COOC2H5PhDNHDNH2 NN PhO七、1. A B COHCOOH OC CH3COOHO OHCO CH3OC DNCH3 CH3CH3CH32. A BNHCH3NCH3CH3 CH3+OH-B3 . CH3OC CH2CH2COOH CH2COOHCH2COOH6D.C.CH3 CCH2CH2COOCH3O OCH3CH3CH3 CCH2CH2CH2OHOCH3OCH3E. O O CH3CH3
