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固体含砷废料的稳定性及处理方法_付一鸣.pdf

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1、cI|:1007-967X(2002)04-0042-04%8c “l #) ZE 付一鸣,王德全,姜 澜,戴 军,金 曼(v, a +110004)K 1: “# ,%8c “l #) ZE 11。 %8c “l / ,8 = “、 “ 、 ; “、c “ M S F%8c “#) ZET。1oM:%8c “l ;) ZEms |:X705 DS M :A1 T “ 1 , “ (c 510-6。X$k c “ 300,Btnc “ ?C。 、 # 8 “d “ B“ 5: 4 |V/ 4; B; “7A |) n ; P 3 6。 t58VY Mv,9 E 。 7, “# v , F1 c

2、 “ 。 “ -,8 “ ,c “ b v 1 pM .。yN,8 c “ ) s3c “ M M,1 “ -830%),8l, 8, b,V rs ;c “6%/c “ M M1,S Fibn1。4 “ i M4,c “ s j。 jc “l e H, WSF %8c “l e。Z %8c “l NZE,%8c “l #) ZE。c = “、 ; “ “ +%8c “l ,| F r,| M1 T%。700 / “ ?vv4 ,1Z s, V 。“ -,c NMN “$ % “K T。c “l ) c “ MS F c NMN “。 M1,YVS F% “。 ID:1 N.L.Piret.T

3、he removal and safe disposal of arsenic in copperprocessingJ, JOM,1999(9):1617.2 A.J.Monhemiusand P.M.Swash.Removing and stabilizing ar-senicfromcopperrefining circuitsby hydrothermalprocessingJ,JOM,1999,51(9):3033.3 P.M.Swash, A.J.Monhemius and J.M.Schaekers.Solubilities44 8 18 of process residues

4、from biological oxidation pretreatments of re-fractory goldoresM, MinorElements 2000, C.A.Young(edi-tor), Soc.Min.Met.Expl., Littleton, CO, U.S.A , 2000:115122.4 R.G.Robins.The solubility of metal arsenicsJ, MetallurgicalTransactions B,1981(12)B:103109.5 T.Nishimura andK.Tozawa.Removalfromwastewater

5、by addi-tionofcalciumhydroxideandstabilizationof arsenic-bearing pre-cipitates by calcinationM, Impurity ControlandDisposal, A.J.Oliver(editor), Canadian Institute of Mining, Metallurgy andPetroleum, Montreal, Canada,1985:3/13/17.6 M.Stefanakisand A.Kontopoulos.Productionof environmentallyAcceptable

6、 arsenites-arsenates from solid arsenic trioxide M,Arsenic Metallurgy Fundamentals and Applications, P.B.Que-neau(editors), The Minerals, Metals and Materials Society,Warrendale, PA, U.S.A., 1988:314316.7 R.G.Robins.Arsenic hydrometallurgyM, Arsenic MetallurgyFundamentals and Applications, P.B.Quene

7、au(editors), TheMinerals, Metals andMaterialsSociety, Warrendale, PA, U.S.A., 1988:215247.8 R.G.Robins.The stability and solubility of ferric arsenate:anupdateM, EPD Congress 90, D.R.Gaskell(editor), TheMinerals, MetalsandMaterialsSociety, Warrendale, PA, U.S.A.,1990:93104.9 E.Krause andV.A.Ettel.So

8、lubilities andstabilitiesof ferric ar-senate compoundsJ, Hydrometallurgy, 1989(22):311337.10 G.B.Harris and S.Monette.The disposal of arsenic solidresiduesM, Productivity and Technology in the MetallurgicalIndustries, M.KochandJ.C.Taylor(editors), The Minerals,Metals and Materials Society, Warrendal

9、e, PA, U.S.A.,1989:545560.11 P.M.Swash and A.J.Monhemius.Synthesis, characterizationandsolubility testing of solids in the Ca-Fe-AsO4 systemM, Subdury95-Mining and the Environment, T.P.Hynesand M.C.Blanchette(editors),CANMET,Ottawa, Canada,1995:1728.TheStabilityandDisposal Methodsof SolidArsenicBear

10、ingWastesFU Yi-ming,WANG De-quan, JIANg Lan,DAI Jun,JIN Man(Northeastern University, Shenyang 110004, China)Abstract:Thestability anddisposalmethodsofsolid arsenicbearingwastesareimportantforenvironment pollu-tiondue to the toxicity of arseniccompounds.Determination technology for stability of theso

11、lid arsenicwasteswasintroduced.Common solid arsenic bearing wastes include arsenic trioxide, calcium arsenate, arsenic sul-phide, arsenicferrihydriteand scordite residues.Stability and disposal methods of the arsenicwastes were re-viewed.Keywords:solidarsenicbearing aastes;stability;disposalmethod g 454 B :%8c “l #) ZE

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