1、最新一代聚丙烯透明剂谢春平博士，美利肯化工,内容简介 Outline,Millad 3988i, Millad NX8000产品概述 Product SummaryMillad NX8000介绍 What is Millad NX8000?Millad NX8000个例经济分析 Millad NX8000 Commercial Case Study总结 Conclusion,十多年来，Millad 3988一直是透明聚丙烯市场的百尺竿头Millad 3988,the Industry Benchmark for Clear PolypropyleneMillad NX8000 更进一步Mill
2、ad NX8000 is for the Ultimate in Clear Polypropylene,Millad NX8000 的产品定位position in the market,Millad NX8000 是透明聚丙烯领域的重大突破。其所能达到的透明度增加了许多商机。Millad NX8000 gives a new clarity standard for cPP, a breakthrough in PP transparency, permitting attractive opportunities in market value growth through the de
3、velopment of new clear resins 通过取代别的透明塑料来加速聚丙烯的增长Accelerating PP growth through material replacement of clear polymers 在已存在的应用通过提高顾客对更为透明产品的兴趣来增长Reinvigorating and growing polypropylene in existing applications through improved consumer interest and acceptance,What is Millad NX8000?Millad NX8000是一全新
4、分子结构的透明剂 Millad NX8000 is a new-to-the-world clarifier based on a new type chemistry that significantly expands the performance of PP clarification,Millad NX8000使得透明聚丙烯看起来近似聚苯乙烯和聚碳酸酯因而使材料取代成为可能 Millad NX8000 allows polypropylene to approach the look and clarity of high clarity plastics like polystyr
5、ene and polycarbonate creating material substitution opportunities 商业级树脂在全球各地都有开发 Commercial grades are in development in each region of the world,Haze Continuum for Selected Plastic Materials,Millad NX8000 使聚丙烯更接近透明工程塑料 Millad NX8000 allows PP to close the haze gap on “water white” polymers,5,PMMA,
6、PET,PS,PC,Glass,Clarified (NX8000) PP(RACO & HOMO)3.5-7.0,Clarified PP (1G) RACO20-30,Clarified (3G) PP (HOMO)15-20,Clarified (3G) PP (RACO) 10-15,Clarified (3G) mPP (HOMO)13-16,Clarified (3G) mPP (RACO) 9-11,Unclarified PP(HOMO) 50-70,Unclarified PP (RACO) 40-50,Unclarified HDPE 80+,“Water White”Cl
7、arity (13),Evolutionary Improvements in Polypropylene Clarity,Note: 1.25 mm plaques,Haze, %,40,80,60,20,10,3,1,5,0,Millad NX8000 的价值何在？What is the Value?,提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型周期 Improved cycle time,Millad NX8000 的价值何在？What is the Value?,提高透明度 Improved clarity增宽加工窗口
8、 Broad processing window缩短成型周期 Improved cycle time,透明聚丙烯在注塑产品的应用Markets for Injection Molded Clear PP,新一代聚丙烯透明剂有何不同？Millad NX8000将 Millad 3988i 的雾度降低几乎一半 Millad NX8000 gives half the haze as Millad 3988i at any thickness.,Millad NX8000 把不同厚度产品的雾度都几乎降低了一半 Millad NX8000 delivers significantly improved
9、 haze at all thickness in IM (50%) under commercial conditions Millad NX8000 显著地增宽了加工区间从而使得雾度在各种操作条件下都接近一致 Millad NX8000 has a significantly broadened processing window - allowing for consistently superior clarity across all polypropylene melt flows and processing conditions,要点 Points to note,Note:
10、DOEs conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm,雾度 Haze,For the Ultimate in Clear Polypropylene,For the Ultimate in Clear Polypropylene,Millad NX8000 的价值何在？What is the Value?,提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型周期 Improved cycle time,新一代聚丙烯透明剂有何不
11、同？ What is Next Generation Millad?Millad NX8000在各种条件下都能得到好的雾度 A broad processing window giving excellent haze under all processing conditions.,Note: DOEs conducted in 12 MFI RCP; Millad NX8000 at 4000 ppm,Millad NX8000 的价值何在？What is the Value?,提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型
12、周期 Improved cycle time,Millad NX8000结晶温度更高，成型周期更短,产能提高 5-10%Millad NX8000 has a higher Tc and shorter T1/2. When coupled with the broader processing window, productivity enhancements (generally 5 10%) are possible without reducing other quality requirements.,Note: Expts conducted in 12 MFI RCP; Mill
13、ad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm,Tc Data,T1/2 Data,Millad NX8000 的价值何在？What is the Value?,提高挤出吹塑产品的透明度EBM - Improved clarity拓宽挤出吹塑的加工窗口EBM - Improved processing window,透明聚丙烯在挤出注塑产品的应用Markets for Extrusion Blow Molded Clear PP,Millad NX8000 使挤出注塑瓶的外形大为改观从而加宽了透明聚丙烯在挤出注塑领域的应用 Millad NX80
14、00 yields new PP aesthetics in EBM bottles permitting a broader application of cPP in EBM applications.Millad NX8000 在雾度和光泽度都有显著提高 Millad NX8000 gives superior performance in haze and gloss at high loadings.,Millad NX8000显著提高挤出注塑产品的外观Millad NX8000 consistently gives improved aesthetics in EBM,要点 Poi
15、nts to note,Note: Expts conducted in 2 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm, 500 mL Shampoo bottle,雾度 Haze,内部光泽度 Inside Gloss,硬度略有提高，抗冲击不受影响 There is a modest improvement in stiffness without loss in impact resistance硬度在低温操作条件下有所提高，抗冲击不受影响 Stiffness is higher at cooler operat
16、ing temperatures without the loss in impact resistance,Millad NX8000具有典型无规共聚的硬度/抗冲击平衡Millad NX8000 has typical stiffness/impact balance for RCP.,要点 Points to note,Note: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm,Flexural Modulus,Gardner Impact,优异的重复加工稳定性,宜于回收利
17、用 Excellent multi-pass additive stability indicates regrind stability,Millad NX8000在氧化裂解中具有优良的稳定性Millad NX8000 has excellent regrind and visc-breaking stability,要点 Points to note,Note: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm,Normal 12 MFI,CR to 35 MFI,Milla
18、d NX8000，其他性质类似Millad 3988i All other attributes are like Millad 3988i.,For the Ultimate in Clear Polypropylene,NX8000 商业化个案研究：更高的透明度在食品包装的价值The Value of Clarity in Food Storage Containers,应用： 食品包装 Application: Food Storage Containers 加工：注塑 Process: Injection Molding 区域：北美 Region: North America 追求高清
19、晰度的动力何在？ Drivers for higher clarity: (1) 增加销售 Increase sales 市场研究表明顾客希望更为透明的食品包装 Market research demonstrates that consumers prefer higher clarity in food storage containers (2) 提高利润率 Improve margins市场研究表明顾客愿意为更透明的食品包装付出多一些 结果证明了这一点 Market research suggests that consumers will pay more for higher cl
20、arity in food storage containers. It has been proved by market.,食品包装盒转换:高清晰度导致高利润率 Food Storage Conversion: Improve Clarity to Improve Margins,成本增加了2美分 Higher clarity adds less than $0.02 / part in cost (assume a $300/ton upcharge for NX8000) 零售价增加了20美分 Retail price is $0.20 / part higher for the Ea
21、sy Find Lids,商业应用举例：,食品容器：高端顾客对更高透明度的追求包装材料：取代高成本塑料如聚碳酸酯，聚氯乙烯，聚苯乙烯，共聚聚酯 (PETG)等 婴儿奶瓶：取代聚碳酸酯 成本及内分泌腺的安全考虑 挤吹塑料瓶：化妆品容器等,For the Ultimate in Clear Polypropylene,Millad NX8000 材料取代的经济分析 Millad NX8000 Economics Inter-material substitution,Source: IDES, data for Oct 07,材料取代商机Material Substitution Opportun
22、ities,聚苯乙烯类 Styrenics (including SAN, SBC)CD盒，杯子，包装等 CD cases, appliances, cups, packaging取代动力 Drivers成本，抗冲击，持久性 Cost (copolymers), impact, sustainability聚酯 Polyesters包装，杯子，瓶子 Packaging, cups, bottles取代动力 Drivers 成本， 手感 Cost (PETG), hand/feel聚碳酸酯 Polycarbonate婴儿奶瓶，水瓶，家具，日常用具Infant feeding bottles, w
23、ater packaging, furniture, housewares, appliances取代动力 Drivers 成本及内分泌腺的安全考虑 Cost, BPA endocrine disruption聚氯乙烯 PVC瓶子 Bottles 环保考虑 Driven by environmental pressure,Millad NX8000 荣获2008年R&D100创新奖,R & D 1 0 0 创新奖（R & D 1 0 0 Awards）是美国科学技术创新奖。R&D 是研究与发展（R e s e a r c h & Development）的缩写,100是指这一奖项的目的：每年在
24、全球范围内，选出优秀的新技术、新产品100 项。今年是第46届。曾获此奖的著名产品：防锁死刹车系统(Anti Lock Brake System, 1969) ，自动取款机(1973) ，传真机(1975) ，液晶显示(1980) ，紫杉醇抗癌药(1993) ，高清晰电视(1998)，等等。Millad NX8000的获奖是透明改性行业对社会贡献的肯定。,颁奖仪式,颁奖仪式,总结 Conclusions,一种全新的聚丙烯透明剂已上市 A novel clarifying agent chemistry is launched更高的透明度使得聚丙烯能和其他透明塑料竞争 Performance w
25、ill allow polypropylene to compete with water white amorphous polymers like PVC, PS, PVC, PET and SAN on an aesthetics basis将使透明聚丙烯更快地增长 Will allow cPP to grow faster as a materialNX8000树脂已经商业化 NX8000 resin is commercially available全球注册正在进行中 All appropriate global chemical & food contact regulatory clearances are either complete or in progress,谢谢各位THANK YOU,
