1、 : 8 3 ! 7 ( CX09B_023Z) ,S E 1 S ( 20974076) ;T e : ( 1977- ) , o , v 5% 401 bf L 6 Ullumann Q , AB2 8 (4null null4#, 4null= Yan ? C DB V Y V 4 8 F 1 ,j M ( Tg) “ 9 v A 14 bPenczek 15 EHO T , (ACE) 8 (AM) Q T bm 6null EHO 0 7 Figure 6null The cationic ringnullopening polymerization of EHO v 0 7 Q V
2、 c b 1, 1, 1null J d (TMP) Q ,s F MHO P Y V 0 7 ! s 0 HBPE 16 bRahm 17 L Y = ? , F E P EH O 0 7 HBPE, M n/Mw 1null2 1null4b 3 . ,Y V e Y = ? V x ? b + M , + 8 M ? C (n m 7), P 0 7 ! HBPE ? Z , 3, 3null= J null (BHMO) 18 3null 2null 2null( 2null Y )Y Y J null3nullJ (HEMO) 19 HBPEb 8 ! HBPE s 0 , C EH
3、O MHO F ! HBPE 4 s 0 Z E b Bednarek 20| a 2 ?v (diEOX)F EHO , BF3 % Et2O b / HBPE, s 0 BH q / EH O1 bYe 21 8 MH O 3null2null2null(2nullJ Y )Y nullY J null3nullJ (MEMO) 7 ! HBPE, 1 MHO % , MH O 30%4 70%, DB 0null1489 v 0null236, Mn 5600 6800b1null2null 2null | 0 Q null B . AB2 8 , Frey 22 n Q Y V 7 E
4、 (ROMBP) ! B , i Q b V , 8 F , e 8 / ? 4 1 V e s 0 s , i V E Q ? 3 , P s 1null5, 13 C NMR V DB 0null53 0null59b7 Kainthan 4 8 / ? 4 1 ! HBPE,Mn V r 700000 23b ROMBPE ! HBPE 1 B Q bT Q : 24a B D %99%null 10 null null s null null 0 null null Y null null m 7null + 0 7 8Figure 7null Several monomers for
5、 cationic ringnullopening polymerization ( d 3 Y ) (P( POnullbnullEO) 25 aY Y Y ( PEOnullbnull( lnullPG) 26a2, 2#, 4, 4#null = E Y b 8 1null3 J ? aDMF DMSO , V s THF A ;7 8 4 F H V DMF DMSO b ? C 4 a 8 i Q H W V V 3 Y bGPCs V 9 F 8 i a Q H W V 4 s 0 b; s V Z T 1 5 _ O H o o , 1 Z E B ) b ? 8 V ? bSr
6、inivasa Rao 381 B ; = ? 8 , s Y ( 4null + 1 b2 null 超支化聚醚的应用研究2null1null 5 p 39| ; , v s 0 ,? C%101%null 10 null null s null null 0 null null Y null null m 12null d J ? 8 Figure 12null Structures of diazirine functionalized monomers 1null4 d A i / T a q , a T 0 b = 40| B Q J = s e 3 B b E F / 0 ? ,
7、? C i 0 q V r 0null 612( 10- 3S/ cmb E 3 g 2 5V,V 0 1 p bYe | MHO MEMO 7 HBPE , MHO 1 30% H K v 0 q , 30 80 H s Y 8null0( 10- 5S/cm 7null4 ( 10- 4 S/cm 21b2null2null 3 D 0 5 Kainthan 41 s Y 1, 2null E J Y = ? | s T 8 b 9 , L V , 4 r 1g/kg H , 3 Y . Y V e s 0 Y = ? v s 0 c , V e , 25 34h M , d b 9 bv
8、 2 ? v i ? A HBPE T , i V Y V B e 7 B - 0 . bHong 42 HBPE , , A Y V 1 F V / T s 0 ( 10nm)b N 0 8 , ? C L “ H Z U y 0 d b ? bWan EHO Y ! ( HPnullgnullPEO) , A 1F HPnullgnullPEO a T Y = ? D / T , R (NP) 43 b 0 A ( PBS) ,? C PBS i T , P NP V e d b q bBurakowska 44 T V ; , 5 , V r M Q 0 s 0 null Z 8 bY
9、V ; ? N , ) , V r d b = Z 8 s 0 , | 0 . 5 4 B r bTziveleka 45 1 e HBPE s , DNA Q 8 b T A U , % V C , Y (PEI)M rT b7 Zhang 46 HBPE , s 0 PEI ! , L ? C AU DNA z ? , y V r Z ( 1 B PEI 4 , V n B “ 3 y 8 5 A U v N b / A V , R , ? C , R 3 M 3 V ,i U ? , V . 47bA e V # Y 2 ? V 4 b L V , i 0null02mg/ml A (
10、F 3 : b 1 1)1) F 3 r q 3 s 100 2null95% 48b F % 5 C PMHO P V r s a 49b9 t ! e ( HBPOnullSO3 ), 8 C z F ? , H % z % M , a A ( 8 = b HBPOnullSO3 “ 8 j l 100nm, O l s 0 ? ,y N T , 0 8 . N 50b T Y V 1 F ? A U F ) , # z e d b: 0 ? 51 b HBPE D , # ? , 3 D 0 5 V k bVargas | 0 a / ! , 8 V 7 p 52 b 2 ? 3 V A
11、 4 F 0 , ? Y 0 %102% null null s null null 0 null null Y null null 2010 M 10 null , R j 53b2null3null V Huck 54 ? ) Si/SiO2 V s 0 , 110 / ? 7 , V Si/ SiO2 V b 8 V Y , K v V r 70nmb V 4 o bWang 55 P V J ,i Q 3 , P EHO 7 V b 4 s ? A , V s Y ? o _ , TMFbZhou 56 , 5 2 ? v (MWNTnullOH),7 | 0 7 N , 5 V ,
12、L C , 5 e b MWNTnullOH 1 q V HBPE MWNT V b MWNT aDMSOaDMF J ? z s ? ,7 O V ? s 0 ; s 0 6B ! ? b2null4null ; ? s 0 5 N, Nnull= J HBPE, V C Y ; s 0 null 0 null f r , V ; ; s 1 57bZhang 6 9nullx J ? 4 c x 3 v ; HBPEb; ? C , ; HBPE ? null? V ? 3 s 0 = ? % M M ,V C Z 8 ? 8 “ + b K v l ? o s Y 393nm 450nm
13、bSrinivasa Rao ! c HBPEs, 510 575nm ; + 38 b2null5null Rokicki 58| HBPE s , : Y Y 4 : i , ,c 20% 25% % 4 (TETA) 20% HBPE A U K v bMnulllhaupt 25 ( d 3 Y ) 3 , # = M HBPE | 0 M Y ? 63 ;, HBPE V ! ; M ? 64 ; , : HBPEV C V I K “ , V A nullA , A null% M M 65b7 HBPE T 66, 67a ! 68a d ! 69 a; % p 70 # , !
14、 71 5 9 X n b%103%null 10 null null s null null 0 null null Y null null 3 null 展望 1 1 v s 0 e , ? v s 0 z aT ? v + b“ B + , HBPE s 0 = a 3 M z ,N s 0 v i , P HBPE b M “ M 1 , HBPE v s 0 | $ ! 9 , ? 5 9 | B Z b参考文献: 1 null Kulkarni A S, Beaucage G. Macromol Rapid Commun, 2007, 28: 1312 1316. 2 null U
15、 hrich K E, Hawker C J, Frnullchet J M J. Macromolecules, 1992, 25: 4583 4587. 3 null Mueller A, Kowalewski T , Wooley K L. M acromolecules, 1998, 31: 776 786. 4 null Insik I, Lee H, Kim S Y. Macromol Chem Phys, 2003, 204( 13) : 1660 1664. 5 null Baek J B, Chien L C. J Polym Sci, Part A: Polym Chem, 2004, 42: 3587 3603. 6 null f L . Polyether; Synthesis; Application%105%null 10 null null s null null 0 null null Y null null
