1、 襄阳市 第五中学 2017 届高 三年 级 9 月月考 化学 试题 24 8 100 90 :Z#xx#k.Com H 1 C 12 N 14 O 16 Cl 35.5 Ca 40 45 9 2 18 1 A B C D 2 A 35 35 17 Cl B C H S H D SiO 23 0.02 mol A H 2 0.02g B 2.408 10 23 C H 2 0.224L D H 2 0.04mol Na H 2 4 A KSCN Fe 3+ Fe 2+B C Na + K +D CO 25 A B C D 6 A B D E ( ) A A E B A CuO E B CO C
2、 A NaOH E CO 2 B NaHCO 3 D A AlCl 3 E 7 A B C D 8 3 A B C D 13 9 C 4 H 8 O 3 CH 3 CH 2 OH CH 3 COOH C 4 H 6 O 2 C 4 H 8 O 3 A HOCH 3 COOCH 2 CH 3B CH 3 CH(OH)CH 2 COOH C HOCH 2 CH 2 CH 2 COOH D CH 3 CH 2 CH(OH)COOH 9 3 27 10 A B C D 11 H 2 S CuSO 4 H 2 S H 2 S Cl 2 A Na 2 SO 3 B HI C NaOH D H 2 O 12
3、 O 2 F 2 H 2 S+4O 2 F 2 6 +2HF+4O 2 A B O 2 F 2 C 4.48 L HF 0.8 mol D 1 4 13 A H 2 SO 3 K 1 =1.3 10 -2K 2 =6.3 10 -8 H 2 CO 3 K 1 =4.2 10 -7 K 2 =5.6 10 -11 H 2 SO 3 NaHCO 3 H 2 SO 3 +2HCO 3 - =SO 3 2- +2CO 2 2 O B pH 910 NaClO NaCN CN - 2CN - +5ClO - +2H + =N 2 2 - +H 2 O C Pb(CH 3 COO) 2 H 2 S Pb
4、2+ +H 2 +D CuSO 4 Cu 2+ +4NH 3 H 2 O=Cu(NH 3 ) 4 2+ +4H 2 O 14 X Fe FeO CuO MnO 2 KCl K 2 CO 3 X Y Z Y Z AgNO 3 Z pH A X FeO B Y Fe CuO C Z KCl K 2 CO 3 D Y MnO 215 A 293 116 Lv 293 B H 2 O H 2 S C D 16 A B C 6 H 12 O 6 6H 2 O 24e 6CO 2 24H +C H + D 1mol CO 2 22.4 L 17 500 10L CO 2(g) +3H 2(g) CH 3
5、OH(g)+H 2 O(g) H=-25kJ mol -1 0.55 :Zxxk.Com A B 0.9 b l C 500 K = 3 10 2D : : * * 18 NH 3 NH 3 2 O K=1.8 10 -5 Ksp Mg(OH) 2 =1.8 10 -11 1.0 L 2.0 10 -4mol L -1 MgCl 2 NH 3 NH 3 A 112mL B 224mL C 118.72 mL D 201.6 mL 55 19 22 23 24 19 10 Mg 2 Cu 2 Fe 2 Al 3 NH 4 K Cl HCO 3 SO 4 2 0.4mol 0.3mol 0.45m
6、ol 0.3mol 0.2mol 1 2 _ 3 : _ _ 0.4mol 0.45mol 4 H 20 (10 ) ) A B C D E X Y Z M N W H K X B C H 2 O 1 Y E 2 3 C 2.0g 250mL 25.00mL KI 0.1mol L -1 Na 2 S 2 O 3 2Na 2 S 2 O 3 +I 2 =Na 2 S 4 O 6 +2NaI Na 2 S 2 O 3 20.00mL 21 (11 ) CH 3 CHO CH 3 CHO + 2Cu(OH) 2+ NaOH CH 3 COONa + Cu 2 2 O NaOH 0.5 mL 40%
7、 2%CuSO 4 10%NaOH pH 1 2 mL : 3 56 2 a 15 78 3 1 mL 1 mL 910 4 b 2 mL 1112 5 1 mL 3 mL : ZXXK 1213 1 a b A 15 1 mL B 2 mL 1 mL C 15 2 mL D 2 mL 2 m L 2 1 Cu 2 (OH) 2 SO 4 Cu 2 (OH) 2 SO 4 1 2 NaOH 3 3 CuO Cu 2 O 4 4 Cu 2 O Cu 2+ Cu 4 5 Cu(OH) 2 OH - Cu(OH) 4 2- Cu(OH) 4 2- pH10 22 12 1 H 2 (g) CO(g)
8、 CH 3 OH(l) 285.8 kJ mol -1 283.0kJ mol -1 726.5 kJ mol -1 (CH 3 OH) _ 2 EFC (TiO 2 ) TiO 2 ( ) _ _ ( 3 K=1 10 -4 20.00mL0.1000mol L -1 NaOH c(HCOOH)=c(HCOO - ) c(H + )=_mol L -1 _40.00mL( _ 4 K sp (BaSO 4 )=1.1 10 -10 50.00 mL0.009 mol L -1 Ba(NO 3 ) 2 50.00 mL 0.010mol L -1 c(Ba 2+ )=_ mol L -1 pH
9、=_ 23 3 12 1 4s 1 _ Cu + _ 2 s _ d _ 3 CaO CaO Ca 2+ _ 4 (KN 3 ) N 2 2KN 3 (s)=2K(l)+3N 2 (g) _( A NaN 3 KN 3 B 2 C D 5 (TiO 2 ) O 2 CN - CNO - CN - _ CNO - _ 6 CrCl 3 CrCl n (H 2 O) 6 n x (n x R H) CrCl n (H 2 O) 6 n x +xR- x CrCl n (H 2 O) 6 n +xH + 0.0015 molCrCl n (H 2 O) 6 n x R H H 0.1200 mol/L NaOH 25.00 mL _ 24 5 (12 ) M PET R 1 A 28 A B 2 B 3 I _( ) a b 4 B C D a 1mol B 1 mol C b C D Br 2 CCl 4 c D NaOH B C 5 6 C 16 7 II
