1、 2017 I 1 Q CO2 5 -1 KOH 100 mL, A.16Q B.8Q C.4Q D.2Q 2 (H2) (CO) (C8H18) (CH4) H2(g)+ 2 1 O2(g)=H2 -1CO(g)+ 2 1 O2(g) =CO2 -1C8H18(l)+ 2 25 O2(g) =8CO2(g)+9H2 -1CH4(g)+2O2(g) =CO2(g)+2H2 -1 H2 CO C8H18 CH4 A.H2(g) B.CO(g) C.C8H18(l) D.CH4(g) 3 100 g CO 3 1 CO2 3 2 C(s)+ 2 1 O2(g)=CO(g) -1 ,CO(g)+ 2
2、 1 O2(g)=CO2 -1 A.392.92 kJ B.2 489.44 kJ C.784.92 kJ D.3 274.3 kJ 4 299 K N2 g +3H2(g) =2NH3 92 -1 , 0.1 mol N2 0.3 mol H2 A. 92.0 kJ B. 92.0 kJ C. 92.0 kJ D. 5 A. B. -1 2H2(g)+O2(g)=2H2 -1C.Ba(OH)2 2O(s)+2NH4Cl(s) =BaCl2(s)+2NH3(g)+10H2 0 D. mol -1 0.5 mol H2SO4 1 mol NaOH 57.3 kJ 6 SO2 N(CH3)42SO
3、4(s) SO2 SO2 N(CH3)42SO4(s) + SO2 N(CH3)42S2O6(s) H 0 N(CH3)42SO4(s) SO2 ( ) A B C D 7 6CO2(g)+6H2O(g) C6H12O6(s)+6O2(g)-2816 kJ A 2816 kJ B 1 mol 24 mol C D 8 H 4g) 2O2(g) =CO2(g) 2H2O(g) H1 CH4g) 2O2(g) =CO2(g) 2H2O(l) H2 H2SO4( )= Na2SO4(aq) +H2O(l) H3 NaOH(aq) + CH3COOH (aq)= CH3COONa (aq) +H2O(
4、l) H4 A H1 H2 H3 H4 B H1 H2 H3 H4 C H1 H2 H3 H4 D H1 H2 H3 H4 9 101 kPa CO HCOOH CH4 CH3OH 67.6 kJ/mol 62.8kJ/mol 890.3 kJ/mol 726kJ/mol A CO(g) O2(g) CO2(g) H 67.6 kJ/mol B HCOOH(1) O2(g) CO2(g) H2O(1) H 62.8 kJ/mol C CH4g) 2O2(g) CO2(g) 2H2O(g) H 890.3 kJ/mol D 2CH3OH(l) 3O2(g) 2CO2(g) 4H2O(l) H 1
5、452 kJ/mol 10 A 0.1 mol/L 20 mL 0.1 mol/L NaOH pH B 2SO2(g) + O2( g) t2 C Ba(OH)2 Ba(OH)2 20 mL Ba(OH)2 D H2(g)+C12(g)=2HCl(g) 183 kJ mol 11 A 2H2 g O2 g = 2H2O g 483 6 kJ/mol 241 8 kJ/mol B C s = C s 0 C 20 0g NaOH 28 7 kJ NaOH aq HCl aq =NaCl aq H2O aq 57 4 kJ/mol D 2C s 2O2 g =2CO2 g 2C s O2 g =2
6、CO g 12 101kPa - -1 - -1 A B C Na O2 Na2O Na2O D 10l kPa -317 kJ/mol II 13 H2 H H Q1 1 H O Q3 1 O2 Q2 1 (1) 4 2 (2) 1 molH2 _ 14 2015 52 1 CH4 CH4(g)+2NO2(g) N2(g) 1 2NO2(g) 1 CH4 N2O4(g) N2 H2O(l) 2 CO(g) H2O(g) CO2(g) 1 2L 2.0molCO(g) 2.0molH2O(g) tmin 32.8kJ t min H2 CO2(g) H2(g) CO(g) H2O(g) 1.0
7、molCO2 1.0molH2 kJ 3 Al2(SO4)3 SO2 Al2(SO4)3 Al2(SO4)3 a. b. KMnO4 c. 5% H2O2 d. 15 C( ) H2(g) )+ O2(g) CO(g) =- -1 2(g)+ O2(g) H20(g) =- -1 )+O2(g) CO2(g) =-394. -1 1 ( 2 02 ( ) a b c 3 2H20(g) 2H2(g)+02(g) = -1 4 C( )+02(g) C02(g) =- -1 ( 5 H20(g) 2 mol H-O 926.0 kJ 1 mol 02(g) 498.0 kJ 1 mol H2(g
8、) H-H KJ 6 CO(g) H2O(g) C02(g) H2(g) 16 CO H2 4 g + 2 1 O2(g) =CO(g)+2H2 1= -1 4(g)+H2O(g) =CO(g)+3H2 2 -1 (O2 21%) 17 (1)Fe2O3(s)+3CO(g)=2Fe(s)+3CO2 -1(2)3Fe2O3 s +CO(g)=2Fe3O4(s)+CO2 -1(3)Fe3O4(s)+CO(g) =3FeO(s)+CO2 -1 FeO(s) CO Fe CO2 1.A CO2 KOH KOH C4H10 4CO2 8KOH 0.5 mol Q 2.B 1 gH2 CO C8H18 C
9、H4 2 1 28 1 114 1 518 kJ 16 1 kJ B 3.C 100 g CO 3 1 12 100 1 mol g g CO 3 1 12 100 1 mol g g -1 =784.92 kJ 4.A 5.D 101 kPa 1 mol Ba( OH)2 2O NH4Cl H2SO4 NaOH 6.B 7.B 8.B H2O(g)H2O(l) CH4g) NaOH H2SO4 H2SO4 CH3COOH H H 9.C 101kPa 1mol 101 kPa C A B 1molCO HCOOH D 2molCH3OH 10.B 11.D 12.D Q1 Q2 Q3 Q3 (2Q1 Q2) (2)H2(g) O2(g)=H2O(l) H (4Q3 Q4) (2Q1 Q2 1 2 mol 1 mol 2 mol 2 mol 14. 1 898 1 2 0.4 t 1 2 2.25 2 24.6 3 3 3 cd 2 Al2(SO4)3 2 15. 1 2 b 3 484.0 4 5 435.0 6 CO(g) H2O(g) CO2(g) H2(g) H 1 17.FeO(s)+CO(g) =Fe(s)+CO2 -1