1、 2 A NH 4 Cl Cl B 94 144 Pu Pu 144 94C S 2 D 2 3 A HI(g) 2 1 H 2 (g)+ 2 1 I 2 (s) H = -26.5kJ/mol 1mol HI 26.5kJ B C(s)+ 2 1 O 2 (g)=CO(g) H= 110.5kJ/mol 110.5kJ/mol C D CaCO 3 (s) = CaO(s) + CO 2 (g) H = +178.5kJ/mol E E 4 N A A 16g O 2 O 3 N A B 1.8 g (D 2 O) N AC lmol Na 2 O 2 4N A D 11.2L 0.5N A
2、5 A Al 3+ 4NH 3 H 2 O=AlO 2 - 4NH 4 + 2H 2 O B SO 2 ClO- SO 2 H 2 O=HClO HSO 3 - C CuSO 4 2Na Cu 2+ 2H 2 O=2Na + Cu(OH) 2 H 2 D HNO 3 3Fe 8H + 2NO 3 -=3Fe 2+ 4H 2 O 6 B 2 O 3 +2Al+3H 2 Al 2 O 3 +B 2 H 6 A B Al 2 O 3 C B 2 H 6 D 1mol B 2 H 6 6mol 7 A Cu 2+ Al 3+ NO 3 SO 4 2 B KSCN K + NH 4 + Cl I C A
3、l 3+ AlO 2 SO 4 2 Na +D pH=3 Na + Cl - Fe 2+ ClO - : 8 X Y Z W Q : ZXXK X Y Z W Q A X W W X -2 B Q W Z C Y Z NaOH D Y W Y Q 9 CO 2 2 C O O A 4 B 5 C 6 D 8 10 O 2 KClO 4 (s) 4Fe(s) KCl(s) 4FeO(s) H A H0 B :Z.xx.k.Com C KClO 4 (s) 8e KCl(s) 4O 2 (l) D 1 mol FeO 8 mol 11 A B C D Cl 2 HCl NH 4 Cl NH 4 C
4、l CO 2 CCl 4 12 A c(OH )=c(H + )=10 6B pH=7 C D 13 X Y Z W ( ) A X HNO 3 W Fe B W O 2 X S C Al 3+ +4OH =AlO 2 +2H 2 O D W O 2 Z CO 214 :Zxxk.Com A pH=7 NH 4 Cl c c(NH 4 + ) c(H + B 0.1mol L 1 NaHA pH=4 H 2 A C pH 11 NaOH pH 3 D 0.1mol L 1 c(OH )/c(NH 3 H 2 O) 15 A B A (g)+xB(g 2C(g) A 8min B 20min A
5、 0.05mol/(L min ) C x=1 30min D 40min 16 NO 3mol/L NaOH 5.1g A NaOH V100mL B NO 2.24L C 9.6g m 3.6g D HNO 3 0.4mol 第 卷 非选择题 （共 52 分） 二、填空 题 17 (14 ) Mg 2+ Fe 3+ Al 3+ Cu 2+ Na + SO 2 4 OH Na 2 O 2 1 DE 2 : 3 4 OA : AB = 5 n mol 6 E 0.5mol 2L Mg(OH) 2 K sp =1.810 11 c(Mg 2+ )= mol/L 18 (12 ) SO 2 NO
6、SO 2 NO Na 2 S 2 O 4 NH 4 NO 3 (Ce ) 装 置 I 装 置 II 装 置 III电 解 槽 装 置 IV NO ，SO 2 NO NaOH 溶 液 Ce 3+ 、NO 2 - 、NO 3 - NO 2 - 、NO 3 - NH 4 NO 3 NH 3 、O 2 Ce 4+ S 2 O 4 2- HSO 3 - Ce 4+ 1 2 (H 2 SO 3 HSO 3 SO 3 2 ) SO 2 NaOH pH=5 NaHSO 3 CaCl 2 pH 2 pH 3 4 Ce 4+ Ce 4+ ( ) 5 NO 2 a g L -1 1 m 3 NO 2 NH 4 NO
7、 3 O 2L ( a ) 19 (14 ) 128135 (CH 3 CO) 2 O 138 158( ) 102 139.4( ) 180 135( ) 1 2 NaHCO 3 CO 2 NaHCO 3 3 4 5 2.76 g 7.5 mL 1.08 g/cm 3 m =2.92g 20 (12 ) G A H C 7 H 8 1 A 2 3 4 E 5 F F C O 5 4 3 - +4H + +4e-=S 2 O 3 2- +3H 2 O 5 5600a/23 19 14 1 2 NaHCO3 3 C 4 FeCl 3 5 81.1% 20 12 1 CH 2 =CH 2 2 + Br 2 + HBr 3 4 5 12
