1、 ? sZE 2009 M 04 22 = 1. ? Y2. ? “ZE3. ? -) ZE4. ? sZE1a ? YB? s0 DBTT %JNFUIPBUF Y 0 0=J4 JJJ = ; s0 DBT = oY=J T$)$M01 s0 DBT %JDIMPSWPT 5SJDIMPSGPO 1IPTQIPOJD BDJE s0 T $)$M01 s0 $“4= $“4| s0 T $)014 s0 EFNFUPO Y ; T / ;? T e EFMUBNFUISJO $“4 s0 T$)#S/0 s0 Y + $“4| s0 T $)$M/ s0 Y 8 BUSBJOFJM s0
2、T$)/0 s0 $“4| Y y DBSCBSZM ) b o # 7 3 38 =“ Vr i EY 3 3N7 OYV J 8r BSEX PS9X M 3 Pb =cj0 v = b E“ TZOUIFUJDQZSFUISJOT j0 ? y L a “ - P 1060ml CH2Cl2Y |15minl“1:1H2SO44mlpH vbB V ? Q bA PAH HA AVl H n5NM= oJNM %! %!b|“ M - b! Qb b!A9M b“ A ; ) / H F NM %! %!Ab NM= oJ WW A %!i l“ A1“) = bZErT zi:kr P
3、FS l q b |HAA NM-NM= oJsY%!b“ MNMP= oJd- %!A %! l“ %!A i sbZErTB#“ v“ BQ ? brPCB ) n5- %!F “ NM = oJ- %!A %! l“ %!A i NMsbGPC Es0 E E NPMFDVMBSFYDMTJPODISPNBUPHSBQIZ b s 4 V Vs V r HFMGJMUSBUJPODISPNBUPHSBQIZ($ 1i E HFMQFSNFBUJPODISPNBUPHSBQIZ(1$ b ($Bs vs0 3a V “ 4FQIBEFY“ ! 41 b(1$E1 4 V s0 ss#s d
4、“ ! 4?a oQ 4bGPC aA P an(1$|nA “dn “S V7 l“ “S %! HW3 a|NMP= oJ 4“ 4 |AV r |sA “d“ l“ “S Asb;E ; Ri“ aZ( “ Bt ;M zBbB “ ? sv1“ “Bt+ o j ($_ aJ s -$.4 2 4_ZE 5( adV ? sBBP &i(a) 4,6-b2-J&p y 1,2- &ic =&ia,j J =& 3,3- = o & &i(a,h) x x =J & 7,12- =J a) x B o& #&=J = N-b=& &-d14 ( S) i1,2,3-cd o&p 3- J
5、x ob& d *R c&+ “1000ml9S K 1ml H i 10mg/L8FS10mg/L V60ml CH2Cl2Y |15minl“1mol/LNaOH10mlpH1060ml CH2Cl2Y |15minl“1:1H2SO44mlpHAbundanceTIC: 04512-01.D50.4153.2361.67 63.5165.3566.3967.7168.2369.1269.6870.5770.9172.1674.2275.4475.7075.8777.4477.75 78.2380.4880.7381.4984.0884.8086.2988.9690.9946.00 48.
6、00 50.00 52.00 54.00 56.00 58.00 60.00 62.00 64.00 66.00020004000TimeAbundanceIon 258.00 (257.70 to 258.70): 04406-20.D46.42 46.79 49.0950.20 50.4650.69 51.8256.9157.5959.25 59.3763.3065.23 65.5046.00 48.00 50.00 52.00 54.00 56.00 58.00 60.00 62.00 64.00 66.000500010000TimeAbundanceIon 268.00 (267.7
7、0 to 268.70): 04406-20.D48.6350.4453.23 53.66 56.5261.7063.30 63.5546.00 48.00 50.00 52.00 54.00 56.00 58.00 60.00 62.00 64.00 66.000500010000TimeAbundanceIon 270.00 (269.70 to 270.70): 04406-20.D50.4455.53 58.11 61.70 63.3046.00 48.00 50.00 52.00 54.00 56.00 58.00 60.00 62.00 64.00 66.00020004000Ti
8、meAbundanceIon 292.00 (291.70 to 292.70): 04406-20.D51.27 51.3952.9353.27 53.7254.1254.5955.0555.22 55.49 55. 4 56.7459.4059.67 60.0461.2761.76 66.4646.00 48.00 50.00 52.00 54.00 56.00 58.00 60.00 62.00 64.00 66.000500010000TimeAbundanceIon 302.00 (301.70 to 302.70): 04406-20.D53.2361.7063.5663.9465
9、.41 66.4346.00 48.00 50.00 52.00 54.00 56.00 58.00 60.00 62.00 64.00 66.000500010000TimeAbundanceIon 304.00 (303.70 to 304.70): 04406-20.D53.2463.5764.8365.41 66.4550.00 55.00 60.00 65.00 70.00 75.00 80.00010002000TimeAbundanceIon 328.00 (327.70 to 328.70): 04406-20.D59.2761.1961.7362.23 64.3165.236
10、8.3270.6650.00 55.00 60.00 65.00 70.00 75.00 80.000500010000TimeAbundanceIon 338.00 (337.70 to 338.70): 04406-20.D61.7063.3067.77 68.29 69.18 70.6471.4974.3078.3078.5150.00 55.00 60.00 65.00 70.00 75.00 80.0002000040000TimeAbundanceIon 340.00 (339.70 to 340.70): 04406-20.D61.70 63.32 65.51 67.7768.2
11、669.18 70.65 71.70 74.31 78.3050.00 55.00 60.00 65.00 70.00 75.00 80.00010002000TimeAbundanceIon 362.00 (361.70 to 362.70): 04406-20.D66.0667.0069.1369.7470.7872.2672.41 75.3550.00 55.00 60.00 65.00 70.00 75.00 80.000500010000TimeAbundanceIon 372.00 (371.70 to 372.70): 04406-20.D69.7472.2375.51 77.5
12、0 77.84 81.5850.00 55.00 60.00 65.00 70.00 75.00 80.0002000400060008000TimeAbundanceIon 374.00 (373.70 to 374.70): 04406-20.D69.7472.2475.51 77.50 77.8478.7481.5872.0074.0076.0078.0080.0082.0084.0086.0088.0090.0092.0094.0096.0002000040000TimeAbundanceIon 396.00 (395.70 to 396.70): 04406-20.D71.71 72
13、.13 73.31 75.23 78.33 80.8572.0074.0076.0078.0080.0082.0084.0086.0088.0090.0092.0094.0096.0005000TimeAbundanceIon 406.00 (405.70 to 406.70): 04406-20.D78.30 84.1772.0074.0076.0078.0080.0082.0084.0086.0088.0090.0092.0094.0096.0005000TimeAbundanceIon 408.00 (407.70 to 408.70): 04406-20.D78.3082.8584.1
14、985.0690.36 97.0272.0074.0076.0078.0080.0082.0084.0086.0088.0090.0092.0094.0096.000100200TimeAbundanceIon 498.00 (497.70 to 498.70): 04406-20.D72.0074.0076.0078.0080.0082.0084.0086.0088.0090.0092.0094.0096.00010002000TimeAbundanceIon 508.00 (507.70 to 508.70): 04406-20.D91.0972.0074.0076.0078.0080.0
15、082.0084.0086.0088.0090.0092.0094.0096.0002000TimeAbundanceIon 510.00 (509.70 to 510.70): 04406-20.D91.09PCB a8 1$#8Sn“ SE =SE sbnsZE“ 8 sb &1“ZE (Bt“ o &8 sPCB a9 SC9 1$#9 9 +ZEb($.4ZE($.4 ? MY o | o & ? 8S“ sYB E o o &9 9 F o |9 o &cZE N 1 OY1“ 9 dv OsV 8 Yy0MTM bPCB ($&$%ZEn5“ o &sv s? pE “SDIMPS
16、P“ B +S | +Y S iS wLZ“ 9 “ ib“ S W K9 T9 bPCB 1$#KD9 T 8 9 8 ic T vd O I v)bBtss8 ( V+ZEs “ obyp 3“d U1$#T?sBZ VV s1$# 6BZ _1$# 1 VV1$#T98b 1 AbundanceTIC: 02604-14.D15.1116.9216.9820.4920.5620.6620.7325.0925.1825.9025.9930.7630.9134.7334.8135.7839.7339.9140.75V 5 S“ 16YQMS #_K MS % _ i (ng/ml) _K P
17、g M 1.0 1 1 1,2-= _ 2.0 9 9 = _ 2.0 1 1 3.0 1 1 c 5.0 5 5 x 4.0 5 5 x 8.4 1 1 7.3 1 1 &i (a)x 8.0 5 5 CHRYSENE 5.5 5 5 &i (b)x 6.3 5 5 &i (k)x 4.7 30 30 &i (a) 6.5 5 5 i (1,2,3-cd) 14 5 5 =&i(a,h) x 11 6 6 &i (g,h,i)E 4.5 5 5 10.0012.0014.0016.0018.0020.0022.0024.0026.0028.0030.0032.0034.0036.0038.0
18、0020000400006000080000100000120000140000160000180000200000220000240000260000280000300000320000340000360000380000400000420000TimeAbundanceTIC: 02524-40.D9.1220.3420.5021.6822.3722.6523.5324.60 24.9625.31 25.5025.8627.5627.9028.0128.2929.6629.7330.5130.6630.9832.2533.4734.4834.5434.6635.3735.8036.9137
19、.83 38.1138.4838.9610.00 15.00 20.00 25.00 30.00 35.00 40.0001000020000300004000050000TimeAbundanceTIC: 02604-11.D8.798.989.3513.3014.4415.09 16.9920.5720.7321.4623.7625.1925.5626.0129.9930.7691 34.73 34.7935.0935.6235.7836.06 36.60 36.94 37.57 38.49 38.718539.3939.7339.9140.7610.00 15.00 20.00 25.0
20、0 30.00 35.00 40.0001000020000300004000050000TimeAbundanceTIC: 02604-14.D (*)9.39 14.3843 15.1116.9216.9820.4920.566620.7325.0925.1825.9025.9930.769134.7334.8135.7839.7339.9140.7510.00 15.00 20.00 25.00 30.00 35.00 40.0001000020000300004000050000TimeAbundanceTIC: 02604-15.D (*)8.989.3513.3014.4415.0
21、9 16.9920.5720.7321.4623.7625.1925.5626.0129.9930.7630.90 34.7334.7935.0935.6235.7836.06 36.60 36.94 37.56 38.8439.3839.7339.9040.75 5( -LR -$.4.4ZErAM 1 -$s MJ? 77J A N-NJOJ?NJO =VM ,_ oONb.4s&4* %5L7 4 -I d -I 1 QSZ T .3. s Hb N-NJO d 0 ? $*%7F7b 5( -LR s 1000ml “%MY | 5mL8l5mLV r“ LC/MSs sstd-3Ti
22、me0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00%01000.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00%01000.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00%01000.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00%01000.
23、50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00%0100080506taihu-17 5: MRM of 1 Channel ES+ TIC9.64e42.96080506taihu-17 4: MRM of 1 Channel ES+ TIC8.52e44.16080506taihu-17 3: MRM of 1 Channel ES+ TIC1.93e62.70080506taihu-17 2: MRM of 1 Channel ES+ TIC1.87e53.16080506taihu-17 1: MR
24、M of 1 Channel ES+ TIC4.24e43.98MC-YRMC-LFMC-RRMC-LRMC-LW 5( -LR -$ZEB V s( _( 1 5( -3 5(33 O 8 3 Mb-$s H 5( 33i 5( -3T V ?S? -3KV7sT LbyN-$s HKz ? bd ZEB “-$.4.4sZE-$.4.4rAM 1 -$s N-NJO J AYb“ 0-b.4s&4* ,7b 4 -I d -IbT = HW dF7$*%F7 0 0b “ sSEsb“ V r“sb 2 H-std-20ppbTime0.20 0.40 0.60 0.80 1.00 1.2
25、0 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.
26、60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%0100090314acr-15 MRM of 1 Channel ES+ TIC1.34e50.97090314acr-14 MRM of 1 Channel ES+ TIC1.01e50.970.64090314acr-13 MRM of 1 Channel ES+ TIC7.07e40.970.64090314acr-12 MRM of 1 Channel ES+ TIC3.56e40.970.64090314acr-11 MRM of 1 Channel ES+
27、 TIC1.77e40.990.640.8120ppb15ppb10ppb5ppb2ppbyanggongdi-jiaTime0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%0100
28、0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.6
29、0 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%01000.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00%0100090314acr-20 MRM of 1 Channel ES+ TIC7.15e40.99
30、0.64090314acr-19 MRM of 1 Channel ES+ TIC6.85e40.990.65090314acr-18 MRM of 1 Channel ES+ TIC7.73e30.640.480.350.780.991.271.20 1.54 2.862.632.321.94 2.42090314acr-17 MRM of 1 Channel ES+ TIC8.10e30.640.390.190.04 0.780.830.991.36 2.671.64 2.17 2.76090314acr-16 MRM of 1 Channel ES+ TIC1.30e31.010.340
31、.250.140.11 0.44 0.580.550.690.720.831.841.561.341.241.111.451.591.71 1.96 2.972.262.032.072.12 2.692.492.352.42 2.60 2.83090314acr-15 MRM of 1 Channel ES+ TIC1.34e50.97090314acr-14 MRM of 1 Channel ES+ TIC1.01e50.970.64090314acr-13 MRM of 1 Channel ES+ TIC7.07e40.970.64090314acr-12 MRM of 1 Channel
32、 ES+ TIC3.56e40.970.64090314acr-11 MRM of 1 Channel ES+ TIC1.77e40.990.64 0.81std5std4std3std2std1blanksample1sample2spiking1spiking2d ZE= M E3 3_S M Hq/d 3? 3FQ 3Y Y4 | M s_K VrVH-b ZE N bY # “ j1 E F V0 lE ($.4EJ yp %5 s %#8“9N NN VN&$%s 2 M S(#5b地表水中无机元素分析技术江苏省环境监测中心陈素兰内容地表水监测项目涉及方法通用要求分析技术要点 比色法 原子吸收法 原子荧光法 电感耦合等离子发射光谱法 电感耦
