1、电石乙炔法合成氯乙烯单体高汞触媒的现状分析 吴刚强,郎中敏,赵磊琰( = S/v, = h 014010)K 1:氯乙烯单体(VCM)主要用来合成聚氯乙烯(PVC)。聚氯乙烯是世界五大工程塑料之一,聚氯乙烯在各行各业具有十分广泛的应用。由于能源结构形式和潜在的成本优势,目前,我国氯乙烯单体工业合成工艺主要以电石乙炔法为主。但该法催化剂高汞触媒的使用会带来系列问题,是其发展的瓶颈。本文指出了高汞触媒一系列弊端,对其现状进行了分析,并对电石乙炔法氯乙烯单体合成工艺催化剂的发展趋势进行了展望。1oM:氯乙烯;电石乙炔法;氯化汞;催化剂ms |:TQ222.4+23 DS M :AcI|: 1006
2、7981(2011)23 0031 02 M , “S 6 y 9,y,/ , %B5 ?Z 。1 FY E FY E BH L, n5 3 F 3 F, FQ 3Y ,Y o _ ob4T/FQ 3 oY,KF QPVC。1 /:CaO+ 3C CaC2+COCaC2+ 2H2O Ca(OH)2+ C2H2C2H2+HClb4CH2=CHClnCH2=CHClCH2-CHClnE/ Es , S= 1 .d oYZE。 ?v、l?、b4o P / 。2 ob4C2.1 汞资源现状 B , Mh 。S + :% , , 1v;% 1 v,72.1% , V7% ;、 3 , % S9% 20%
3、;C1 3 ,h 。2008 M,S =PVC 881.7t, FEPVCL= 75%。 FEPVC3V, 31t PVC ob4h 1. 0 1.2kg。Y 9, -S = Mh ob48000t,|hXr500t,S =h9 50% ,V oh 15%。h 1“PVC/ , V 3; o B, 3 PV, o 6 , VE b ; H,31 2011 M23 内蒙古石油化工l : 2011- 10- 15 “:内蒙古科技大学青年创新基金(2009NC025,2010NC023)。Te:吴刚强(1978- ),内蒙古土左旗人,在读博士。QV o$Y ,Q ! l , lb49 P s ; o
4、( , 3 y,b ? h y;8 / 5, STNS m 。B , / Z :B C ob4, PV ;7 7?db4,9 ob4。XTV Z S , L i 7? db4,B k。 ID1 顾青.我国合成树脂生产现状及“十一五”规划J.中国塑料,2006,20(6): 1 7.2 王云彩.汞污染对人体健康的危害J.生活与健康,2004,(3): 21 23.3 MartinLodenius; Pekka Nuorteva; Sirkka-Liisa Nuorteva. Up take ofmercury by ter-restrial plants-observations in Finl
5、and andSlovenia in the years 1979- 1981. Materialsand Geoenvironment, 2004, 51(2): 11811184.4 Jaroslav Reif;Jan Prusa;VladimirMejsirik.Survey of Land Contaminated with Mercuryat PVC-SODA FactoryinVlora,Albania.Materials and Geoenvironment, 2004,51(1):220 228.5 Cullaj A.; Lazo P.;Baraj B. Investigati
6、 onofMercury ContaminationinVloraBay(Alba-nia). Materials and Geoenvironment, 2004,51(1): 58 62.Current Analysis on High- mercury Catalyst of Calcium Carbide AcetyleneSynthesize Vinyl Chloride MonomerWU Gang- qiang,LANG Zhong- min, ZHAO Lei- yan(Instituteof chemistryandChemical Engineering, InnerMon
7、golia University of Scienceand Technology, Baotou014010, Inner Mongolia, China)Abstract: Vinylchloridemonomer(VCM) ismainlyusedsyntheticpolyvinylchloride(PVC). PVCisone of theworlds fivemajor engineering plastics, it has avery wide range of applications inall walks oflife. As theenergystructureandth
8、epotentialcost advantages, Chinas industrialsynthesis of vinylchlo-ridemonomermainlycalciumcarbideacetylenebasedatpresent. However, themethodusinghighmercurycatalyst will bring aseries of issues, whichis thedevelopment bottleneck. This paperpoints out thehigh-mercury catalyst a series of drawbacks,thecatalyst status was analyzed,andcalcium carbideacetylenevinyl chloridemonomersynthesis catalyst trendwas predicted.Key words:Vinyl Chloride;Calcium Carbide Acetylene Method;Mercuric Chloride;Catalyst32 内蒙古石油化工 2011 M23
